Power of infrared and raman spectroscopies to characterize metal-organic frameworks and investigate their interaction with guest molecules

KI Hadjiivanov, DA Panayotov, MY Mihaylov… - Chemical …, 2020 - ACS Publications
The variety of functionalities and porous structures inherent to metal-organic frameworks
(MOFs) together with the facile tunability of their properties makes these materials suitable …

Coordinatively unsaturated metal sites (open metal sites) in metal–organic frameworks: design and applications

Ü Kökçam-Demir, A Goldman, L Esrafili… - Chemical Society …, 2020 - pubs.rsc.org
Metal–organic frameworks (MOFs) can contain open metal sites (OMS) or coordinatively
unsaturated sites (CUS) or open coordination sites (OCS) when vacant Lewis acid sites on …

Tuning the structure and function of metal–organic frameworks via linker design

W Lu, Z Wei, ZY Gu, TF Liu, J Park, J Park… - Chemical Society …, 2014 - pubs.rsc.org
Metal–organic frameworks (MOFs) are constructed from metal ions/clusters coordinated by
organic linkers (or bridging-ligands). The hallmark of MOFs is their permanent porosity …

Metal–organic and covalent organic frameworks as single-site catalysts

SMJ Rogge, A Bavykina, J Hajek, H Garcia… - Chemical Society …, 2017 - pubs.rsc.org
Heterogeneous single-site catalysts consist of isolated, well-defined, active sites that are
spatially separated in a given solid and, ideally, structurally identical. In this review, the …

Vapor-phase metalation by atomic layer deposition in a metal–organic framework

JE Mondloch, W Bury, D Fairen-Jimenez… - Journal of the …, 2013 - ACS Publications
Metal–organic frameworks (MOFs) have received attention for a myriad of potential
applications including catalysis, gas storage, and gas separation. Coordinatively …

Recent advances in post-synthetic modification of metal–organic frameworks: New types and tandem reactions

Z Yin, S Wan, J Yang, M Kurmoo, MH Zeng - Coordination Chemistry …, 2019 - Elsevier
In the past five years, post-synthetic modification (PSM) has become a very useful strategy in
systematically functionalizing metal–organic frameworks (MOFs) by modifying the linker …

An assessment of strategies for the development of solid-state adsorbents for vehicular hydrogen storage

MD Allendorf, Z Hulvey, T Gennett, A Ahmed… - Energy & …, 2018 - pubs.rsc.org
Nanoporous adsorbents are a diverse category of solid-state materials that hold
considerable promise for vehicular hydrogen storage. Although impressive storage …

Hydrogen storage in metal-organic frameworks: a review

HW Langmi, J Ren, B North, M Mathe, D Bessarabov - Electrochimica Acta, 2014 - Elsevier
Metal-organic frameworks (MOFs) for hydrogen storage have continued to receive intense
interest over the past decade. MOFs are a class of organic-inorganic hybrid crystalline …

Amide-functionalized metal–organic frameworks: Syntheses, structures and improved gas storage and separation properties

DX Xue, Q Wang, J Bai - Coordination Chemistry Reviews, 2019 - Elsevier
Abstract Metal–organic frameworks (MOFs), emerging as a new type of solid state porous
material, have received intensive attention in academia and industry over the last two …

Sintering-resistant single-site nickel catalyst supported by metal–organic framework

Z Li, NM Schweitzer, AB League… - Journal of the …, 2016 - ACS Publications
Develo** supported single-site catalysts is an important goal in heterogeneous catalysis
since the well-defined active sites afford opportunities for detailed mechanistic studies …