Oxide–and silicate–water interfaces and their roles in technology and the environment

JL Bañuelos, E Borguet, GE Brown Jr… - Chemical …, 2023 - ACS Publications
Interfacial reactions drive all elemental cycling on Earth and play pivotal roles in human
activities such as agriculture, water purification, energy production and storage …

Water structure in the electrical double layer and the contributions to the total interfacial potential at different surface charge densities

B Rehl, E Ma, S Parshotam… - Journal of the …, 2022 - ACS Publications
The electric double layer governs the processes of all charged surfaces in aqueous
solutions; however, elucidating the structure of the water molecules is challenging for even …

Water capture mechanisms at zeolitic imidazolate framework interfaces

JC Wagner, KM Hunter, F Paesani… - Journal of the American …, 2021 - ACS Publications
Water capture mechanisms of zeolitic imidazolate framework ZIF-90 are revealed by
differentiating the water clustering and the center pore filling step, using vibrational sum …

A new imaginary term in the second-order nonlinear susceptibility from charged interfaces

E Ma, PE Ohno, J Kim, Y Liu, EH Lozier… - The Journal of …, 2021 - ACS Publications
Nonresonant second harmonic generation (SHG) phase and amplitude measurements
obtained from the silica–water interface at varying pH values and an ionic strength of 0.5 M …

Sum frequency generation spectroscopy of fluorinated organic material-based interfaces: a tutorial review

S Sakunkaewkasem, D Deleon, Y Choi, HV Tran… - Analyst, 2023 - pubs.rsc.org
Molecular interactions at interfaces have a significant effect on the wetting properties of
surfaces on a macroscale. Sum frequency generation (SFG) spectroscopy, one of a few …

Divalent ion specific outcomes on Stern layer structure and total surface potential at the silica: water interface

E Ma, FM Geiger - The Journal of Physical Chemistry A, 2021 - ACS Publications
The second-order nonlinear susceptibility, χ (2), in the Stern layer and the total interfacial
potential drop, Φ (0) tot, across the oxide: water interface are estimated from SHG amplitude …

Carbonate-Terminated Self-Assembled Monolayers for Mimicking Nanoscale Polycarbonate Surfaces

P Tajalli, JM Hernandez Rivera… - ACS Applied Nano …, 2023 - ACS Publications
Two carbonate-terminated alkanethiol molecules having different positional isomers of a six-
membered cyclic carbonate group, 3-COC12SH and 2-COC12SH, were synthesized and …

Antifouling coatings generated from unsymmetrical partially fluorinated spiroalkanedithiols

LR St. Hill, JW Craft Jr, P Chinwangso… - ACS Applied Bio …, 2021 - ACS Publications
Biofouling negatively impacts modern society on a daily basis, especially with regard to the
important industries of medicine, oil, and ship**. This manuscript describes the …

Polarizable cesium cations for energy storage from electrolyte characterization to-EDLC application

G Nikiforidis, M El Yagoubi, M Anouti - Electrochimica Acta, 2022 - Elsevier
In the quest for new electrolytes on electrochemical energy storage devices, we present,
characterize and test a simple organic electrolyte based on cesium bis …