Dehydroamino acid residues in bioactive natural products

S Wang, K Wu, YJ Tang, H Deng - Natural Product Reports, 2024 - pubs.rsc.org
Covering: 2000 to up to 2023 α, β-Dehydroamino acids (dhAAs) are unsaturated
nonproteinogenic amino acids found in a wide array of naturally occurring peptidyl …

Exploring the diverse landscape of biaryl-containing peptides generated by cytochrome P450 macrocyclases

H Nam, JS An, J Lee, Y Yun, H Lee… - Journal of the …, 2023 - ACS Publications
Cytochrome P450 enzymes (P450s) catalyze diverse oxidative cross-coupling reactions
between aromatic substrates in the natural product biosynthesis. Specifically, P450s install …

Proteases involved in leader peptide removal during RiPP biosynthesis

SM Eslami, WA van der Donk - ACS Bio & Med Chem Au, 2023 - ACS Publications
Ribosomally synthesized and post-translationally modified peptides (RiPPs) have received
much attention in recent years because of their promising bioactivities and the portability of …

Bacterial Cytochrome P450 Catalyzed Post‐translational Macrocyclization of Ribosomal Peptides

BB He, J Liu, Z Cheng, R Liu, Z Zhong… - Angewandte Chemie …, 2023 - Wiley Online Library
Ribosomally synthesized and post‐translationally modified peptides (RiPPs) are a
fascinating group of natural products that exhibit diverse structural features and bioactivities …

An intramolecular macrocyclase in plant ribosomal peptide biosynthesis

LS Mydy, J Hungerford, DN Chigumba… - Nature chemical …, 2024 - nature.com
The biosynthetic dogma of ribosomally synthesized and posttranslationally modified
peptides (RiPP) involves enzymatic intermolecular modification of core peptide motifs in …

Deciphering the ABA and GA biosynthesis approach of Bacillus pumilus, mechanistic approach, explaining the role of metabolic region as an aid in improving the …

S Shaffique, AA Shah, P Odongkara, HO Elansary… - Scientific Reports, 2024 - nature.com
Bacillus pumilus plays an essential role in agricultural applications as a beneficial microbe
and for sustainable agriculture production. However, the underlying mechanisms of B …

Plant peptides–redefining an area of ribosomally synthesized and post-translationally modified peptides

JR Chekan, LS Mydy, MA Pasquale… - Natural Product …, 2024 - pubs.rsc.org
Covering 1965 to February 2024Plants are prolific peptide chemists and are known to make
thousands of different peptidic molecules. These peptides vary dramatically in their size …

Functional and Promiscuity Studies of Three-Residue Cyclophane Forming Enzymes Show Nonnative C–C Cross-Linked Products and Leader-Dependent …

AFL Suarez, TQN Nguyen, L Chang… - ACS Chemical …, 2024 - ACS Publications
Enzymes catalyzing peptide macrocyclization are important biochemical tools in drug
discovery. The three-residue cy clophane-f orming e nzyme s (3-CyFEs) are an emerging …

Peptide crosslinking by a class of plant copper enzymes

MROK Noyon, S Hematian - Trends in Chemistry, 2024 - cell.com
BURP domain peptide cyclases, or BpCs (an abbreviation we recommend in this opinion),
are an emerging class of copper enzymes which catalyze the oxidative macrocyclization of …

Reassignment of the Structure of a Tryptophan‐Containing Cyclic Tripeptide Produced by the Biarylitide Crosslinking Cytochrome P450blt

LJ Coe, Y Zhao, L Padva, A Keto… - … A European Journal, 2024 - Wiley Online Library
The structure of the sidechain crosslinked Tyr‐Leu‐Trp peptide produced by the biarylitide
crosslinking cytochrome P450Blt from Micromonospora sp. MW‐13 has been reanalysed by …