Recent progress in the science of complex coacervation

CE Sing, SL Perry - Soft Matter, 2020 - pubs.rsc.org
Complex coacervation is an associative, liquid–liquid phase separation that can occur in
solutions of oppositely-charged macromolecular species, such as proteins, polymers, and …

Block copolymer electrolytes for lithium metal batteries: Strategies to boost both ionic conductivity and mechanical strength

T Wang, L Zhong, M **ao, D Han, S Wang… - Progress in Polymer …, 2023 - Elsevier
The mechanically hard phase and ionically conductive phase endow suitably designed
block copolymer electrolytes (BCPEs) with the “Janus” property, thus providing the …

Metal‐Halogen Interactions Inducing Phase Separation for Self‐Healing and Tough Ionogels with Tunable Thermoelectric Performance

W Zhao, Y Zheng, A Huang, M Jiang… - Advanced …, 2024 - Wiley Online Library
Ionic liquid‐based thermoelectric gels become a compelling candidate for thermoelectric
power generation and sensing due to their giant thermopower, good thermal stability, high …

50th Anniversary Perspective: Block PolymersPure Potential

CM Bates, FS Bates - Macromolecules, 2017 - ACS Publications
Block polymers have undergone extraordinary evolution since their inception more than 60
years ago, maturing from simple surfactants to an expansive class of macromolecules …

Structure and nanostructure in ionic liquids

R Hayes, GG Warr, R Atkin - Chemical reviews, 2015 - ACS Publications
Much of chemistry is concerned with the study of reactions and processes in solution, that is,
where liquids are used as solvents. 2, 3 The solvent is the (excess) liquid phase in which …

Mg2B2O5 Nanowire Enabled Multifunctional Solid-State Electrolytes with High Ionic Conductivity, Excellent Mechanical Properties, and Flame-Retardant …

O Sheng, C **, J Luo, H Yuan, H Huang, Y Gan… - Nano …, 2018 - ACS Publications
High ionic conductivity, satisfactory mechanical properties, and wide electrochemical
windows are crucial factors for composite electrolytes employed in solid-state lithium-ion …

Development of the modern theory of polymeric complex coacervation

CE Sing - Advances in colloid and interface science, 2017 - Elsevier
Oppositely charged polymers can undergo the process of complex coacervation, which
refers to a liquid–liquid phase separation driven by electrostatic attraction. These materials …

Anion exchange membranes with fast ion transport channels driven by cation-dipole interactions for alkaline fuel cells

W Yu, J Zhang, X Liang, X Ge, C Wei, Z Ge… - Journal of Membrane …, 2021 - Elsevier
Polyethylene glycol (PEG)-grafted imidazolium-containing flexible-side-chain type anion
exchange membrane (AEM) has been designed and fabricated for efficient anion exchange …

Ion correlations drive charge overscreening and heterogeneous nucleation at solid–aqueous electrolyte interfaces

SS Lee, A Koishi, IC Bourg, P Fenter - Proceedings of the National …, 2021 - pnas.org
Classical electrical double layer (EDL) models are foundational to the representation of
atomistic structure and reactivity at charged interfaces. An important limitation to these …

Molecular connectivity and correlation effects on polymer coacervation

M Radhakrishna, K Basu, Y Liu, R Shamsi… - …, 2017 - ACS Publications
Our ability to predict the thermodynamic phase behavior of a material system is a direct
reflection on our understanding of the relevant interactions. Voorn–Overbeek (VO) theory …