Chiral metal–organic frameworks
In the past two decades, metal–organic frameworks (MOFs) or porous coordination polymers
(PCPs) assembled from metal ions or clusters and organic linkers via metal–ligand …
(PCPs) assembled from metal ions or clusters and organic linkers via metal–ligand …
Recognition in the domain of molecular chirality: from noncovalent interactions to separation of enantiomers
It is not a coincidence that both chirality and noncovalent interactions are ubiquitous in
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …
Chiral supramolecular polymers
As an active branch within the field of supramolecular polymers, chiral supramolecular
polymers (SPs) are an excellent benchmark to generate helical structures that can clarify the …
polymers (SPs) are an excellent benchmark to generate helical structures that can clarify the …
Possible chemical and physical scenarios towards biological homochirality
The single chirality of biological molecules in terrestrial biology raises more questions than
certitudes about its origin. The emergence of biological homochirality (BH) and its …
certitudes about its origin. The emergence of biological homochirality (BH) and its …
Light-empowered contra-thermodynamic stereochemical editing
PZ Wang, WJ **ao, JR Chen - Nature Reviews Chemistry, 2023 - nature.com
Creating, conserving and modifying the stereochemistry of organic compounds has been the
subject of significant research efforts in synthetic chemistry. Most synthetic routes are …
subject of significant research efforts in synthetic chemistry. Most synthetic routes are …
Vibrational circular dichroism spectroscopy of chiral molecular crystals: insights from theory
S Jähnigen - Angewandte Chemie International Edition, 2023 - Wiley Online Library
Chirality is a curious phenomenon that appears in various forms. While the concept of
molecular (RS‐) chirality is ubiquitous in chemistry, there are also more intricate forms of …
molecular (RS‐) chirality is ubiquitous in chemistry, there are also more intricate forms of …
Chiral Molecular Cage with Tunable Stereoinversion Barriers
WB Gao, Z Li, T Tong, X Dong, H Qu… - Journal of the …, 2023 - ACS Publications
The manipulation of chirality in molecular entities that rapidly interconvert between
enantiomeric forms is challenging, particularly at the supramolecular level. Advances in …
enantiomeric forms is challenging, particularly at the supramolecular level. Advances in …
Catalytic deracemization reactions
M Huang, T Pan, X Jiang, S Luo - Journal of the American …, 2023 - ACS Publications
Deracemization, which converts a racemate into its single enantiomer without separation of
the intermediate, has gained renewed interest in asymmetric synthesis with its inherent …
the intermediate, has gained renewed interest in asymmetric synthesis with its inherent …
Chiral stationary phases and applications in gas chromatography
G Betzenbichler, L Huber, S Kräh, MLK Morkos… - Chirality, 2022 - Wiley Online Library
Chiral compounds are ubiquitous in nature and play a pivotal role in biochemical processes,
in chiroptical materials and applications, and as chiral drugs. The analysis and …
in chiroptical materials and applications, and as chiral drugs. The analysis and …
Strategies for chiral separation: from racemate to enantiomer
J Sui, N Wang, J Wang, X Huang, T Wang, L Zhou… - Chemical …, 2023 - pubs.rsc.org
Chiral separation has already become a crucial topic for effectively utilizing superfluous
racemates synthesized by chemical means and satisfying the growing requirements for …
racemates synthesized by chemical means and satisfying the growing requirements for …