Structured catalysts and catalytic processes: transport and reaction perspectives

C Pei, S Chen, D Fu, ZJ Zhao, J Gong - Chemical Reviews, 2024 - ACS Publications
The structure of catalysts determines the performance of catalytic processes. Intrinsically, the
electronic and geometric structures influence the interaction between active species and the …

Single-atom catalysts across the periodic table

SK Kaiser, Z Chen, D Faust Akl, S Mitchell… - Chemical …, 2020 - ACS Publications
Isolated atoms featuring unique reactivity are at the heart of enzymatic and homogeneous
catalysts. In contrast, although the concept has long existed, single-atom heterogeneous …

Peripheral-nitrogen effects on the Ru1 centre for highly efficient propane dehydrogenation

Y Zhou, F Wei, H Qi, Y Chai, L Cao, J Lin, Q Wan… - Nature Catalysis, 2022 - nature.com
Single-atom catalysts with uniform metal active sites show potential for selectivity control.
However, their application to high-temperature propane dehydrogenation remains …

Dual-Atom Catalyst with N-Colligated Zn1Co1 Species as Dominant Active Sites for Propane Dehydrogenation

Y Chai, S Chen, Y Chen, F Wei, L Cao… - Journal of the …, 2023 - ACS Publications
Dual-atom catalysts (DACs) with paired active sites can provide unique intrinsic properties
for heterogeneous catalysis, but the synergy of the active centers remains to be elucidated …

Defective TiOx overlayers catalyze propane dehydrogenation promoted by base metals

S Chen, Y Xu, X Chang, Y Pan, G Sun, X Wang, D Fu… - Science, 2024 - science.org
The industrial catalysts utilized for propane dehydrogenation (PDH) to propylene, an
important alternative to petroleum-based cracking processes, either use expensive metals or …

Propane dehydrogenation: catalyst development, new chemistry, and emerging technologies

S Chen, X Chang, G Sun, T Zhang, Y Xu… - Chemical SOCIETY …, 2021 - pubs.rsc.org
Propylene is an important building block for enormous petrochemicals including
polypropylene, propylene oxide, acrylonitrile and so forth. Propane dehydrogenation (PDH) …

Metal catalysts for heterogeneous catalysis: from single atoms to nanoclusters and nanoparticles

L Liu, A Corma - Chemical reviews, 2018 - ACS Publications
Metal species with different size (single atoms, nanoclusters, and nanoparticles) show
different catalytic behavior for various heterogeneous catalytic reactions. It has been shown …

Direct and oxidative dehydrogenation of propane: from catalyst design to industrial application

JH Carter, T Bere, JR Pitchers, DG Hewes… - Green …, 2021 - pubs.rsc.org
The direct formation of propene from propane is a well-established commercial process,
which on the basis of energy consumption, is environmentally preferred to the current large …

Breaking the scaling relationship via thermally stable Pt/Cu single atom alloys for catalytic dehydrogenation

G Sun, ZJ Zhao, R Mu, S Zha, L Li, S Chen… - Nature …, 2018 - nature.com
Noble-metal alloys are widely used as heterogeneous catalysts. However, due to the
existence of scaling properties of adsorption energies on transition metal surfaces, the …

Aromatics production via methanol-mediated transformation routes

T Li, T Shoinkhorova, J Gascon, J Ruiz-Martinez - ACS Catalysis, 2021 - ACS Publications
The methanol-to-aromatics (MTA) process is regarded as a promising route to produce
aromatic commodities through non-petroleum carbon resources, such as biomass, waste …