[HTML][HTML] Recent progress and new perspectives on metal amide and imide systems for solid-state hydrogen storage

S Garroni, A Santoru, H Cao, M Dornheim, T Klassen… - Energies, 2018 - mdpi.com
Hydrogen storage in the solid state represents one of the most attractive and challenging
ways to supply hydrogen to a proton exchange membrane (PEM) fuel cell. Although in the …

In Situ Formation of TiB2 Nanoparticles for Enhanced Dehydrogenation/Hydrogenation Reaction Kinetics of LiBH4–MgH2 as a Reversible Solid-State Hydrogen …

F Karimi, MVC Riglos, A Santoru, A Hoell… - The Journal of …, 2018 - ACS Publications
To enhance the dehydrogenation/rehydrogenation kinetic behavior of the LiBH4–MgH2
composite system, TiF4 is used as an additive. The effect of this additive on the hydride …

Structural and kinetic investigation of the hydride composite Ca (BH 4) 2+ MgH 2 system doped with NbF 5 for solid-state hydrogen storage

F Karimi, PK Pranzas, C Pistidda, JA Puszkiel… - Physical Chemistry …, 2015 - pubs.rsc.org
Designing safe, compact and high capacity hydrogen storage systems is the key step
towards introducing a pollutant free hydrogen technology into a broad field of applications …

Enhanced hydrogen storage properties of 2LiNH2/MgH2 through the addition of Mg (BH4) 2

S Qiu, X Ma, E Wang, H Chu, J Huot, Y Zou… - Journal of Alloys and …, 2017 - Elsevier
Abstract The Li–Mg–N–H system has been widely considered as one of the most promising
candidates for on-board hydrogen storage due to its high reversible hydrogen capacity …

Role of aluminum chloride on the reversible hydrogen storage properties of the Li–N–H system

LF Albanesi, S Garroni, PA Larochette, P Nolis… - international journal of …, 2015 - Elsevier
In order to understand the role of AlCl 3 addition on the Li–N–H system, we have
systematically investigated the hydrogen sorption kinetics and the reactions between LiNH 2 …

KNH 2–KH: a metal amide–hydride solid solution

A Santoru, C Pistidda, MH Sørby, MR Chierotti… - Chemical …, 2016 - pubs.rsc.org
We report for the first time the formation of a metal amide–hydride solid solution. The
dissolution of KH into KNH2 leads to an anionic substitution, which decreases the interaction …

A new potassium-based intermediate and its role in the desorption properties of the K–Mg–N–H system

A Santoru, S Garroni, C Pistidda, C Milanese… - Physical Chemistry …, 2016 - pubs.rsc.org
New insights into the reaction pathways of different potassium/magnesium amide–hydride
based systems are discussed. In situ SR-PXD experiments were for the first time performed …

Comparison of the thermochemical and mechanochemical transformations in the 2NaNH2–MgH2 system

G Pireddu, A Valentoni, CB Minella, C Pistidda… - international journal of …, 2015 - Elsevier
We focus on the chemical transformations involved in the 2NaNH 2+ MgH 2 system
subjected to thermal and mechanical inputs. Transformations occurring on the powder …

New insights into the thermal desorption of the 2LiNH2+ KBH4+ LiH mixture

A Valentoni, S Garroni, C Pistidda, E Masolo… - International journal of …, 2014 - Elsevier
In situ two-dimensional synchrotron X-ray powder diffraction investigation combined with
Rietveld method data analysis were performed in order to yield a complete and quantitative …

Effects of metal halides on the sorbitive properties of the system 2LiNH 2+ LiH+ KBH 4.

A Valentoni, G Mulas, S Garroni, S Enzo - researchgate.net
The ternary system 2LiNH 2+ LiH+ KBH 4, according to thermodynamic calculations has
been indicated as an interesting candidate for solid state hydrogen storage for on-board …