O2 Activation by Metal Surfaces: Implications for Bonding and Reactivity on Heterogeneous Catalysts
The activation of O2 on metal surfaces is a critical process for heterogeneous catalysis and
materials oxidation. Fundamental studies of well-defined metal surfaces using a variety of …
materials oxidation. Fundamental studies of well-defined metal surfaces using a variety of …
Surface chemistry of ruthenium dioxide in heterogeneous catalysis and electrocatalysis: from fundamental to applied research
H Over - Chemical Reviews, 2012 - ACS Publications
Ruthenium is a chemical element that can easily adopt various formal oxidation states from−
II to+ VIII in chemical bonds,(1, 2) thus giving rise to many compounds with interesting and …
II to+ VIII in chemical bonds,(1, 2) thus giving rise to many compounds with interesting and …
Catalytic combustion of methane over palladium-based catalysts
Palladium-based catalysts are widely applied in exhaust catalytic converter and catalytic
combustion systems. The mechanism for methane oxidation on a Pd-based catalyst is …
combustion systems. The mechanism for methane oxidation on a Pd-based catalyst is …
Electrochemical behaviour of palladium electrode: Oxidation, electrodissolution and ionic adsorption
In electrochemistry, Pourbaix diagrams also known as potential-pH diagrams map out the
regions of stability of metals as well as the regions of possible existence of stable …
regions of stability of metals as well as the regions of possible existence of stable …
Consequences of Metal–Oxide Interconversion for C–H Bond Activation during CH4 Reactions on Pd Catalysts
Mechanistic assessments based on kinetic and isotopic methods combined with density
functional theory are used to probe the diverse pathways by which C–H bonds in CH4 react …
functional theory are used to probe the diverse pathways by which C–H bonds in CH4 react …
Active sites and mechanisms for H2O2 decomposition over Pd catalysts
A Plauck, EE Stangland, JA Dumesic… - Proceedings of the …, 2016 - National Acad Sciences
A combination of periodic, self-consistent density functional theory (DFT-GGA-PW91)
calculations, reaction kinetics experiments on a SiO2-supported Pd catalyst, and mean-field …
calculations, reaction kinetics experiments on a SiO2-supported Pd catalyst, and mean-field …
Molecular beam experiments on model catalysts
Heterogeneous catalysts are highly complex materials with respect to both their composition
and structure. The reaction kinetics on their surfaces is known to depend sensitively on …
and structure. The reaction kinetics on their surfaces is known to depend sensitively on …
Two-dimensional oxide on Pd (111)
The oxidation of Pd (111) leads to an incommensurate surface oxide, which was studied by
the use of scanning tunneling microscopy, surface x-ray diffraction, high resolution core level …
the use of scanning tunneling microscopy, surface x-ray diffraction, high resolution core level …
Surface chemistry of late transition metal oxides
JF Weaver - Chemical reviews, 2013 - ACS Publications
The surface chemistry of late transition metal oxides is scientifically interesting and can play
a central role in commercial applications of heterogeneous catalysis. The late transition …
a central role in commercial applications of heterogeneous catalysis. The late transition …
Oscillatory CO oxidation on Pd (1 0 0) studied with in situ scanning tunneling microscopy
We have studied the catalytic oxidation of CO on Pd (100) at atmospheric pressures, using a
combined flow reactor and scanning tunneling microscope (STM). By switching from a CO …
combined flow reactor and scanning tunneling microscope (STM). By switching from a CO …