Advances and opportunities in the exciting world of azobenzenes

FA Jerca, VV Jerca, R Hoogenboom - Nature Reviews Chemistry, 2022 - nature.com
Azobenzenes are archetypal molecules that have a central role in fundamental and applied
research. Over the course of almost two centuries, the area of azobenzenes has witnessed …

Noncanonical amino acids in biocatalysis

Z Birch-Price, FJ Hardy, TM Lister, AR Kohn… - Chemical …, 2024 - ACS Publications
In recent years, powerful genetic code reprogramming methods have emerged that allow
new functional components to be embedded into proteins as noncanonical amino acid …

Molecular photoswitches in aqueous environments

J Volarić, W Szymanski, NA Simeth… - Chemical Society …, 2021 - pubs.rsc.org
Molecular photoswitches enable dynamic control of processes with high spatiotemporal
precision, using light as external stimulus, and hence are ideal tools for different research …

Advances in application of azobenzene as a trigger in biomedicine: molecular design and spontaneous assembly

HB Cheng, S Zhang, J Qi, XJ Liang… - Advanced …, 2021 - Wiley Online Library
Azobenzene is a well‐known derivative of stimulus‐responsive molecular switches and has
shown superior performance as a functional material in biomedical applications. The results …

Step** out of the blue: from visible to near‐IR triggered photoswitches

Z Zhang, W Wang, M O'Hagan, J Dai… - Angewandte Chemie …, 2022 - Wiley Online Library
Light offers unique opportunities for controlling the activity of materials and biosystems with
high spatiotemporal resolution. Molecular photoswitches are chromophores that undergo …

In Vivo Photopharmacology

K Hull, J Morstein, D Trauner - Chemical reviews, 2018 - ACS Publications
Synthetic photoswitches have been known for many years, but their usefulness in biology,
pharmacology, and medicine has only recently been systematically explored. Over the past …

Heteroaryl azo dyes as molecular photoswitches

S Crespi, NA Simeth, B König - Nature Reviews Chemistry, 2019 - nature.com
We have known of azobenzene for over 150 years, the past 80 of which have seen the study
and application of its photochromism. Azobenzene derivatives are now considered …

Photochromism into nanosystems: towards lighting up the future nanoworld

L Wang, Q Li - Chemical Society Reviews, 2018 - pubs.rsc.org
The ability to manipulate the structure and function of promising nanosystems via energy
input and external stimuli is emerging as an attractive paradigm for develo** …

On the promise of photopharmacology using photoswitches: a medicinal chemist's perspective

MJ Fuchter - Journal of Medicinal Chemistry, 2020 - ACS Publications
Photopharmacology is a growing area of endeavor that employs photoswitchable ligands to
allow for light-dependent pharmacological activity. By coupling light to therapeutic action …

Taking phototherapeutics from concept to clinical launch

BM Vickerman, EM Zywot, TK Tarrant… - Nature Reviews …, 2021 - nature.com
More than four decades have passed since the first example of a light-activated (caged)
compound was described. In the intervening years, a large number of light-responsive …