Molecular plasmonics for nanoscale spectroscopy

MD Sonntag, JM Klingsporn, AB Zrimsek… - Chemical Society …, 2014 - pubs.rsc.org
Surface-and tip-enhanced Raman and LSPR spectroscopies have developed over the past
15 years as unique tools for uncovering the properties of single particles and single …

Density Functional Theory Calculation of pKa's of Thiols in Aqueous Solution Using Explicit Water Molecules and the Polarizable Continuum Model

B Thapa, HB Schlegel - The Journal of Physical Chemistry A, 2016 - ACS Publications
The p K a's of substituted thiols are important for understanding their properties and
reactivities in applications in chemistry, biochemistry, and material chemistry. For a …

Photonics and spectroscopy in nanojunctions: a theoretical insight

M Galperin - Chemical Society Reviews, 2017 - pubs.rsc.org
The progress of experimental techniques at the nanoscale in the last decade made optical
measurements in current-carrying nanojunctions a reality, thus indicating the emergence of …

Tip-enhanced Raman spectromicroscopy on the angstrom scale: bare and CO-terminated Ag tips

N Tallarida, J Lee, VA Apkarian - ACS nano, 2017 - ACS Publications
The tip is key to the successful execution of tip-enhanced Raman scattering (TERS)
measurements in the single molecule limit. We show that nanoscopically smooth silver tips …

Surface-enhanced Raman trajectories on a nano-dumbbell: transition from field to charge transfer plasmons as the spheres fuse

M Banik, PZ El-Khoury, A Nag, A Rodriguez-Perez… - Acs Nano, 2012 - ACS Publications
By taking advantage of the tensor nature of surface-enhanced Raman scattering (SERS), we
track trajectories of the linker molecule and a CO molecule chemisorbed at the hot spot of a …

Bimetallic Ag–Cu Alloy SERS Substrates as Label-Free Biomedical Sensors: Femtomolar Detection of Anticancer Drug Mitoxantrone with Multiplexing

S Kaja, AV Mathews, VVK Venuganti, A Nag - Langmuir, 2023 - ACS Publications
Surface-enhanced Raman spectroscopy (SERS) has been recognized as a promising label-
free technology for clinical monitoring due to its high sensitivity and multiplexing ability …

Bimetallic Ag–Cu alloy microflowers as SERS substrates with single-molecule detection limit

S Kaja, A Nag - Langmuir, 2021 - ACS Publications
Bimetallic Ag–Cu alloy microflowers with tunable surface compositions were fabricated as
surface-enhanced Raman spectroscopy (SERS) substrates with a limit of detection in the …

Dramatic enhancement of tip-enhanced Raman scattering mediated by atomic point contact formation

S Liu, B Cirera, Y Sun, I Hamada, M Müller… - Nano Letters, 2020 - ACS Publications
Tip-enhanced Raman scattering (TERS) in ångström-scale plasmonic cavities has drawn
increasing attention. However, Raman scattering at vanishing cavity distances remains …

Antitags: SERS‐Encoded Nanoparticle Assemblies that Enable Single‐Spot Multiplex Protein Detection

N Guarrotxena, GC Bazan - Advanced Materials, 2014 - Wiley Online Library
Highly sensitive assays that can specifically target several analytes in parallel by using a
single sample, ie, multiplexed, are of interest for improved disease diagnostics,[1, 2] …

Raman scattering at plasmonic junctions shorted by conductive molecular bridges

PZ El-Khoury, D Hu, VA Apkarian, WP Hess - Nano letters, 2013 - ACS Publications
Intensity spikes in Raman scattering, accompanied by switching between line spectra and
band spectra, can be assigned to shorting the junction plasmon through molecular …