N-Heterocyclic Carbene-Stabilized Atomically Precise Metal Nanoclusters

EL Albright, TI Levchenko, VK Kulkarni… - Journal of the …, 2024 - ACS Publications
This perspective highlights advances in the preparation and understanding of metal
nanoclusters stabilized by organic ligands with a focus on N-heterocyclic carbenes (NHCs) …

The concept of active site in heterogeneous catalysis

C Vogt, BM Weckhuysen - Nature Reviews Chemistry, 2022 - nature.com
Catalysis is at the core of chemistry and has been essential to make all the goods
surrounding us, including fuels, coatings, plastics and other functional materials. In the near …

Recent progress on phase engineering of nanomaterials

Q Yun, Y Ge, Z Shi, J Liu, X Wang, A Zhang… - Chemical …, 2023 - ACS Publications
As a key structural parameter, phase depicts the arrangement of atoms in materials.
Normally, a nanomaterial exists in its thermodynamically stable crystal phase. With the …

Recent advances in the chemistry and applications of N-heterocyclic carbenes

P Bellotti, M Koy, MN Hopkinson, F Glorius - Nature Reviews Chemistry, 2021 - nature.com
N-Heterocyclic carbenes, despite being isolated and characterized three decades ago, still
capture scientists' interest as versatile, modular and strongly coordinating moieties. In the …

Imidazolium-functionalized Mo3P nanoparticles with an ionomer coating for electrocatalytic reduction of CO2 to propane

M Esmaeilirad, Z Jiang, AM Harzandi, A Kondori… - Nature Energy, 2023 - nature.com
Propane is a tri-carbon (C3) alkane widely used as a fuel. Despite recent advances in CO2
electrocatalysis, the production of C3+ molecules directly from CO2 is challenging due to …

Nanometre-resolved observation of electrochemical microenvironment formation at the nanoparticle–ligand interface

Y Shan, X Zhao, M Fonseca Guzman, A Jana… - Nature Catalysis, 2024 - nature.com
The dynamic response of surface ligands on nanoparticles (NPs) to external stimuli critically
determines the functionality of NP–ligand systems. For example, in electrocatalysis the …

Defect chemistry in heterogeneous catalysis: recognition, understanding, and utilization

C **e, D Yan, H Li, S Du, W Chen, Y Wang, Y Zou… - Acs …, 2020 - ACS Publications
Heterogeneous catalysis plays an important role in modern industry. Exploring catalysts with
high efficiency, low-cost, and high stability is an important issue for the research of …

N-Heterocyclic carbenes as tunable ligands for catalytic metal surfaces

M Koy, P Bellotti, M Das, F Glorius - Nature Catalysis, 2021 - nature.com
Heterogeneous catalysts represent the backbone of many industrial processes and thus
have a considerable societal impact. The active sites of these heterogeneous catalysts are …

N-Heterocyclic Carbenes in Materials Chemistry

CA Smith, MR Narouz, PA Lummis, I Singh… - Chemical …, 2019 - ACS Publications
N-Heterocyclic carbenes (NHCs) have become one of the most widely studied class of
ligands in molecular chemistry and have found applications in fields as varied as catalysis …

N-Heterocyclic Carbene-Stabilized Hydrido Au24 Nanoclusters: Synthesis, Structure, and Electrocatalytic Reduction of CO2

VK Kulkarni, BN Khiarak, S Takano… - Journal of the …, 2022 - ACS Publications
Atomically precise hydrido gold nanoclusters are extremely rare but interesting due to their
potential applications in catalysis. By optimization of molecular precursors, we have …