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N-Heterocyclic Carbene-Stabilized Atomically Precise Metal Nanoclusters
EL Albright, TI Levchenko, VK Kulkarni… - Journal of the …, 2024 - ACS Publications
This perspective highlights advances in the preparation and understanding of metal
nanoclusters stabilized by organic ligands with a focus on N-heterocyclic carbenes (NHCs) …
nanoclusters stabilized by organic ligands with a focus on N-heterocyclic carbenes (NHCs) …
The concept of active site in heterogeneous catalysis
C Vogt, BM Weckhuysen - Nature Reviews Chemistry, 2022 - nature.com
Catalysis is at the core of chemistry and has been essential to make all the goods
surrounding us, including fuels, coatings, plastics and other functional materials. In the near …
surrounding us, including fuels, coatings, plastics and other functional materials. In the near …
Recent progress on phase engineering of nanomaterials
As a key structural parameter, phase depicts the arrangement of atoms in materials.
Normally, a nanomaterial exists in its thermodynamically stable crystal phase. With the …
Normally, a nanomaterial exists in its thermodynamically stable crystal phase. With the …
Recent advances in the chemistry and applications of N-heterocyclic carbenes
N-Heterocyclic carbenes, despite being isolated and characterized three decades ago, still
capture scientists' interest as versatile, modular and strongly coordinating moieties. In the …
capture scientists' interest as versatile, modular and strongly coordinating moieties. In the …
Imidazolium-functionalized Mo3P nanoparticles with an ionomer coating for electrocatalytic reduction of CO2 to propane
Propane is a tri-carbon (C3) alkane widely used as a fuel. Despite recent advances in CO2
electrocatalysis, the production of C3+ molecules directly from CO2 is challenging due to …
electrocatalysis, the production of C3+ molecules directly from CO2 is challenging due to …
Nanometre-resolved observation of electrochemical microenvironment formation at the nanoparticle–ligand interface
The dynamic response of surface ligands on nanoparticles (NPs) to external stimuli critically
determines the functionality of NP–ligand systems. For example, in electrocatalysis the …
determines the functionality of NP–ligand systems. For example, in electrocatalysis the …
Defect chemistry in heterogeneous catalysis: recognition, understanding, and utilization
Heterogeneous catalysis plays an important role in modern industry. Exploring catalysts with
high efficiency, low-cost, and high stability is an important issue for the research of …
high efficiency, low-cost, and high stability is an important issue for the research of …
N-Heterocyclic carbenes as tunable ligands for catalytic metal surfaces
Heterogeneous catalysts represent the backbone of many industrial processes and thus
have a considerable societal impact. The active sites of these heterogeneous catalysts are …
have a considerable societal impact. The active sites of these heterogeneous catalysts are …
N-Heterocyclic Carbenes in Materials Chemistry
N-Heterocyclic carbenes (NHCs) have become one of the most widely studied class of
ligands in molecular chemistry and have found applications in fields as varied as catalysis …
ligands in molecular chemistry and have found applications in fields as varied as catalysis …
N-Heterocyclic Carbene-Stabilized Hydrido Au24 Nanoclusters: Synthesis, Structure, and Electrocatalytic Reduction of CO2
Atomically precise hydrido gold nanoclusters are extremely rare but interesting due to their
potential applications in catalysis. By optimization of molecular precursors, we have …
potential applications in catalysis. By optimization of molecular precursors, we have …