Cyclopentadienyl cobalt (III) complexes: Synthetic and catalytic chemistry
DA Loginov, LS Shul'pina, DV Muratov… - Coordination Chemistry …, 2019 - Elsevier
Cyclopentadienyl cobalt complexes have been known since 1953. In the recent years, they
have attracted attention of chemists due to their application in C–H activation reactions. The …
have attracted attention of chemists due to their application in C–H activation reactions. The …
1, 1′-Bis (ortho-carborane)-based transition metal complexes
IB Sivaev, VI Bregadze - Coordination Chemistry Reviews, 2019 - Elsevier
The last decade was marked by the growing interest of researchers in the chemistry of 1, 1′-
bis (ortho-carborane) and transition metal complexes based thereof. In this review various …
bis (ortho-carborane) and transition metal complexes based thereof. In this review various …
Palladium Catalyzed Selective B(3)–H Activation/Oxidative Dehydrogenative Coupling for the Synthesis of Bis(o-carborane)s
J Wu, K Cao, CY Zhang, TT Xu, XY Wen, B Li… - Inorganic …, 2020 - ACS Publications
A palladium catalyzed selective B (3)–H activation/oxidative dehydrogenative coupling for
the synthesis of bis (o-carborane) s connected with B (3)–B (3′) and B (3)–B (6′) bonds …
the synthesis of bis (o-carborane) s connected with B (3)–B (3′) and B (3)–B (6′) bonds …
Catalytic Oxidative Dehydrogenative Coupling of Cage B–H/B–H Bonds for Synthesis of Bis(o-carborane)s
J Wu, K Cao, CY Zhang, TT Xu, LF Ding, B Li… - Organic letters, 2019 - ACS Publications
An efficient and succinct protocol for synthesis of bis (o-carborane) connected by a B–B
bond via palladium catalyzed oxidative dehydrogenative coupling of cage B–H/B–H bonds …
bond via palladium catalyzed oxidative dehydrogenative coupling of cage B–H/B–H bonds …
Synthesis of 9-borafluorene analogues featuring a three-dimensional 1, 1′-bis (o-carborane) backbone
The synthesis of [1, 1′-bis (o-carboranyl)] boranes was achieved through the deprotonation
of 1, 1′-bis (o-carborane) reagents followed by salt metathesis with (iPr) 2NBCl2. X-ray …
of 1, 1′-bis (o-carborane) reagents followed by salt metathesis with (iPr) 2NBCl2. X-ray …
Arene–Ruthenium Complexes of 1,1′-Bis(ortho-carborane): Synthesis, Characterization, and Catalysis
RJ Jeans, APY Chan, LE Riley, J Taylor… - Inorganic …, 2019 - ACS Publications
Deprotonation of 1, 1′-bis (ortho-carborane) with n BuLi in THF followed by reaction with
[RuCl2 (p-cymene)] 2 affords, in addition to the known compound [Ru (κ3-2, 2′, 3′-{1-(1 …
[RuCl2 (p-cymene)] 2 affords, in addition to the known compound [Ru (κ3-2, 2′, 3′-{1-(1 …
Synthesis of the First Example of the 12‐Vertex‐closo/12‐Vertex‐nido Biscarborane Cluster by a Metal‐Free B−H Activation at a Phosphorus(III) Center
YO Wong, MD Smith… - Chemistry–A European …, 2016 - Wiley Online Library
Abstract An unusual 12‐vertex‐closo‐C2B10/12‐vertex‐nido‐C2B10 biscarborane cluster
was synthesized through an unprecedented regioselective metal‐free B− H activation by a …
was synthesized through an unprecedented regioselective metal‐free B− H activation by a …
Bis(phosphine)hydridorhodacarborane Derivatives of 1,1′-Bis(ortho-carborane) and Their Catalysis of Alkene Isomerization and the Hydrosilylation of …
APY Chan, JA Parkinson, GM Rosair… - Inorganic …, 2020 - ACS Publications
Deprotonation of [7-(1′-closo-1′, 2′-C2B10H11)-nido-7, 8-C2B9H11]− and reaction with
[Rh (PPh3) 3Cl] results in isomerization of the metalated cage and the formation of [8-(1 …
[Rh (PPh3) 3Cl] results in isomerization of the metalated cage and the formation of [8-(1 …
Unprecedented flexibility of the 1, 1′-bis (o-carborane) ligand: catalytically-active species stabilised by B-agostic B–H⇀ Ru interactions
LE Riley, APY Chan, J Taylor, WY Man, D Ellis… - Dalton …, 2016 - pubs.rsc.org
Doubly-deprotonated 1, 1′-bis (o-carborane) reacts with [RuCl2 (p-cymene)] 2 to afford [Ru
(κ3-2, 2′, 3′-{1-(1′-1′, 2′-closo-C2B10H10)-1, 2-closo-C2B10H10})(p-cymene)](1) in …
(κ3-2, 2′, 3′-{1-(1′-1′, 2′-closo-C2B10H10)-1, 2-closo-C2B10H10})(p-cymene)](1) in …
Advances in the Synthesis of Biscarboranes
K Cao, CY Zhang - European Journal of Organic Chemistry, 2022 - Wiley Online Library
Biscarboranes are comprised of two carborane units linked with a C− C, B− B or C− B bond,
which have important applications in functional materials, coordination chemistry as well as …
which have important applications in functional materials, coordination chemistry as well as …