The upsurge interest in the development of efficient methodologies for the construction of
nitrogen‐containing frameworks via the use of expedient reagents have been creating a …

Nitroso compounds have emerged as highly valuable reaction partners or reagents in
organic synthesis due to their rich reactivity. The versatile profile of these compounds allows …

A (2, 2, 6, 6-tetramethylpiperidin-1-yl) oxyl-mediated difunctionalization of alkenes with tert-
butyl nitrite, P4S10, and alcohols has been developed for the synthesis of β-oximino …

Free radical three-component nitration/spirocyclization of unsaturated sulfonamides/amides
with tert-butyl nitrite was developed for the construction of diverse NO2-revised 4-azaspiro …

Herein, a novel method for the gram-scale synthesis of (E)-quinoxalinone oximes through a
multicomponent reaction under mild conditions is described. Such a transformation was …

Abstract A K2S2O8‐promoted nitration/spirocyclization of biaryl ynones using inexpensive
NaNO2 as nitro source has been described. This cascade reaction is triggered by nitration of …

Nitroaromatics are tremendously valuable organic compounds with a long history of being
used as pharmaceuticals, agrochemicals, and explosives as well as vital intermediates to a …

A visible-light-promoted highly site-selective N 1-alkylation of benzotriazoles with diazo
compounds has been achieved under mild and metal-free conditions. Using cheap, readily …

This work presents an acid-free method for aromatic nitrosation using 2-methoxyethyl nitrite
(MOE-ONO). While originally developed as a NO x radical source in our group, we …

Carbon dioxide (CO2) conversion into value-added chemicals/fuels by utilizing solar energy
is a sustainable way to mitigate our dependence on fossil fuels and stimulate a carbon …