Heterocyclic compounds including the atoms N, O, S, and P have excellent corrosion
inhibition potential due to their ability to coordinate and bond with metallic substrates. For …

Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

In this contribution, we provide a comprehensive overview of C–H activation methods
promoted by NHC–transition metal complexes, covering the literature since 2002 (the year …

Conspectus The photophysics and photochemistry of transition metal complexes (TMCs)
has long been a hot field of interdisciplinary research. Rich metal-based redox processes …

Iron is the most abundant transition metal in Earth, s crust; it is relatively inexpensive, not
very toxic, and environmentally benign. 1 Undoubtedly, due to the involvement in a multitude …

In less than 20 years N-heterocyclic carbenes (NHCs) have become well-established
ancillary ligands for the preparation of transition metal-based catalysts. This is mainly due to …

Cyclic iron tetracarbenes are an emerging class of macrocyclic iron N-heterocyclic carbene
(NHC) complexes. They can be considered as an organometallic compound class inspired …

High-oxidation-state 3d metal species have found a wide range of applications in modern
synthetic chemistry and materials science. They are also implicated as key reactive species …

A 9 ps 3MLCT lifetime was achieved by a FeII complex based on C (NHC)⁁ N (py)⁁ C
(NHC) pincer ligands. This is the longest known so far for any kind of complexes of this …

Abstract The two‐coordinate [(CAAC) 2Fe] complex [CAAC= cyclic (alkyl)(amino) carbene]
binds dinitrogen at low temperature (T<− 80° C). The resulting putative three‐coordinate N2 …