From stable radicals to thermally robust high-spin diradicals and triradicals
Stable radicals and thermally robust high-spin di-and triradicals have emerged as important
organic materials due to their promising applications in diverse fields. New fundamental …
organic materials due to their promising applications in diverse fields. New fundamental …
Molecular magnetism: from chemical design to spin control in molecules, materials and devices
E Coronado - Nature Reviews Materials, 2020 - nature.com
The field of molecular magnetism is rapidly evolving towards the use of magnetic molecules
and molecule-based magnetic materials in physics-driven and nanotechnology-driven …
and molecule-based magnetic materials in physics-driven and nanotechnology-driven …
A Dynamic Triradical: Synthesis, Crystal Structure, and Spin Frustration
X Dong, QC Luo, Y Zhao, T Wang, Q Sun… - Journal of the …, 2023 - ACS Publications
Polyradicals, ie, multispin organic molecules, are playing important roles in radical-based
material applications for their spin–spin interaction. A dynamic covalently bonded multispin …
material applications for their spin–spin interaction. A dynamic covalently bonded multispin …
Conjugated nitroxides
EV Tretyakov, VI Ovcharenko… - Russian Chemical …, 2022 - iopscience.iop.org
In recent years, research dealing with organic paramagnetic compounds such as stable
radicals and high-spin systems has been focused on applied aspects. Several key trends …
radicals and high-spin systems has been focused on applied aspects. Several key trends …
Platform for high-spin molecules: A verdazyl-nitronyl nitroxide triradical with quartet ground state
EV Tretyakov, PV Petunin, SI Zhivetyeva… - Journal of the …, 2021 - ACS Publications
Thermally resistant air-stable organic triradicals with a quartet ground state and a large
energy gap between spin states are still unique compounds. In this work, we succeeded to …
energy gap between spin states are still unique compounds. In this work, we succeeded to …
Spin frustration in organic radicals
S Tang, X Wang - Angewandte Chemie International Edition, 2024 - Wiley Online Library
Spin frustration, which results from geometric frustration and a systematical inability to satisfy
all antiferromagnetic (AF) interactions between unpaired spins simultaneously, is under the …
all antiferromagnetic (AF) interactions between unpaired spins simultaneously, is under the …
High-spin organic diradical with robust stability
Triplet ground-state organic molecules are interesting with respect to several emerging
technologies but typically exhibit limited stability. We report two organic diradicals, one of …
technologies but typically exhibit limited stability. We report two organic diradicals, one of …
Thermally and magnetically robust triplet ground state diradical
N Gallagher, H Zhang, T Junghoefer… - Journal of the …, 2019 - ACS Publications
High spin (S= 1) organic diradicals may offer enhanced properties with respect to several
emerging technologies, but typically exhibit low singlet triplet energy gaps and possess …
emerging technologies, but typically exhibit low singlet triplet energy gaps and possess …
Spin-frustrated trisradical trication of prismcage
Organic trisradicals featuring threefold symmetry have attracted significant interest because
of their unique magnetic properties associated with spin frustration. Herein, we describe the …
of their unique magnetic properties associated with spin frustration. Herein, we describe the …
Synthesis and Thin Films of Thermally Robust Quartet (S = 3/2) Ground State Triradical
C Shu, M Pink, T Junghoefer, E Nadler… - Journal of the …, 2021 - ACS Publications
High-spin (S= 3/2) organic triradicals may offer enhanced properties with respect to several
emerging technologies, but those synthesized to date typically exhibit small doublet quartet …
emerging technologies, but those synthesized to date typically exhibit small doublet quartet …