Bioinspired framework catalysts: From enzyme immobilization to biomimetic catalysis

KY Wang, J Zhang, YC Hsu, H Lin, Z Han… - Chemical …, 2023 - ACS Publications
Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency
and selectivity. However, the structural complexity and vulnerability hamper the application …

Molecular cavity for catalysis and formation of metal nanoparticles for use in catalysis

R Saha, B Mondal, PS Mukherjee - Chemical Reviews, 2022 - ACS Publications
The employment of weak intermolecular interactions in supramolecular chemistry offers an
alternative approach to project artificial chemical environments like the active sites of …

Polarization engineering of covalent triazine frameworks for highly efficient photosynthesis of hydrogen peroxide from molecular oxygen and water

C Wu, Z Teng, C Yang, F Chen, HB Yang… - Advanced …, 2022 - Wiley Online Library
Two‐electron oxygen photoreduction to hydrogen peroxide (H2O2) is seriously inhibited by
its sluggish charge kinetics. Herein, a polarization engineering strategy is demonstrated by …

Design and applications of water-soluble coordination cages

EG Percástegui, TK Ronson, JR Nitschke - Chemical Reviews, 2020 - ACS Publications
Compartmentalization of the aqueous space within a cell is necessary for life. In similar
fashion to the nanometer-scale compartments in living systems, synthetic water-soluble …

Advances in supramolecular host-mediated reactivity

M Morimoto, SM Bierschenk, KT **a, RG Bergman… - Nature Catalysis, 2020 - nature.com
Since the trailblazing discoveries of Lehn, Cram and Pedersen, supramolecular chemistry
has established itself as a cornerstone of organic chemistry. Supramolecular hosts offer …

Increasing structural and functional complexity in self-assembled coordination cages

S Pullen, J Tessarolo, GH Clever - Chemical Science, 2021 - pubs.rsc.org
Progress in metallo-supramolecular chemistry creates potential to synthesize functional
nano systems and intelligent materials of increasing complexity. In the past four decades …

Molecular barrels as potential hosts: from synthesis to applications

R Banerjee, D Chakraborty… - Journal of the American …, 2023 - ACS Publications
Self-assembled discrete molecular architectures that show selective molecular recognition
within their internal cavities are highly desirable. Such hosts often show guest recognition …

Picking the lock of coordination cage catalysis

TK Piskorz, V Martí-Centelles, RL Spicer, F Duarte… - Chemical …, 2023 - pubs.rsc.org
The design principles of metallo-organic assembly reactions have facilitated access to
hundreds of coordination cages of varying size and shape. Many of these assemblies …

New horizons for catalysis disclosed by supramolecular chemistry

G Olivo, G Capocasa, D Del Giudice… - Chemical Society …, 2021 - pubs.rsc.org
The adoption of a supramolecular approach in catalysis promises to address a number of
unmet challenges, ranging from activity (unlocking of novel reaction pathways) to selectivity …

Self-Assembled Pd12 Coordination Cage as Photoregulated Oxidase-Like Nanozyme

S Bhattacharyya, SR Ali… - Journal of the …, 2020 - ACS Publications
Designing supramolecular architectures with uncommon geometries embedded with
functional building units is of immense importance in contemporary research. In this report …