Bioinspired framework catalysts: From enzyme immobilization to biomimetic catalysis
Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency
and selectivity. However, the structural complexity and vulnerability hamper the application …
and selectivity. However, the structural complexity and vulnerability hamper the application …
Molecular cavity for catalysis and formation of metal nanoparticles for use in catalysis
The employment of weak intermolecular interactions in supramolecular chemistry offers an
alternative approach to project artificial chemical environments like the active sites of …
alternative approach to project artificial chemical environments like the active sites of …
Polarization engineering of covalent triazine frameworks for highly efficient photosynthesis of hydrogen peroxide from molecular oxygen and water
Two‐electron oxygen photoreduction to hydrogen peroxide (H2O2) is seriously inhibited by
its sluggish charge kinetics. Herein, a polarization engineering strategy is demonstrated by …
its sluggish charge kinetics. Herein, a polarization engineering strategy is demonstrated by …
Design and applications of water-soluble coordination cages
Compartmentalization of the aqueous space within a cell is necessary for life. In similar
fashion to the nanometer-scale compartments in living systems, synthetic water-soluble …
fashion to the nanometer-scale compartments in living systems, synthetic water-soluble …
Advances in supramolecular host-mediated reactivity
Since the trailblazing discoveries of Lehn, Cram and Pedersen, supramolecular chemistry
has established itself as a cornerstone of organic chemistry. Supramolecular hosts offer …
has established itself as a cornerstone of organic chemistry. Supramolecular hosts offer …
Increasing structural and functional complexity in self-assembled coordination cages
Progress in metallo-supramolecular chemistry creates potential to synthesize functional
nano systems and intelligent materials of increasing complexity. In the past four decades …
nano systems and intelligent materials of increasing complexity. In the past four decades …
Molecular barrels as potential hosts: from synthesis to applications
Self-assembled discrete molecular architectures that show selective molecular recognition
within their internal cavities are highly desirable. Such hosts often show guest recognition …
within their internal cavities are highly desirable. Such hosts often show guest recognition …
Picking the lock of coordination cage catalysis
The design principles of metallo-organic assembly reactions have facilitated access to
hundreds of coordination cages of varying size and shape. Many of these assemblies …
hundreds of coordination cages of varying size and shape. Many of these assemblies …
New horizons for catalysis disclosed by supramolecular chemistry
The adoption of a supramolecular approach in catalysis promises to address a number of
unmet challenges, ranging from activity (unlocking of novel reaction pathways) to selectivity …
unmet challenges, ranging from activity (unlocking of novel reaction pathways) to selectivity …
Self-Assembled Pd12 Coordination Cage as Photoregulated Oxidase-Like Nanozyme
Designing supramolecular architectures with uncommon geometries embedded with
functional building units is of immense importance in contemporary research. In this report …
functional building units is of immense importance in contemporary research. In this report …