Nitric oxide (NO) is an important signaling molecule that is involved in a wide range of
physiological and pathological events in biology. Metal coordination chemistry, especially …

Nanomaterials with enzyme‐like activities, coined nanozymes, have been researched
widely as they offer unparalleled advantages in terms of low cost, superior activity, and high …

Single‐atom catalysts (SACs) have attracted extensive attention in the catalysis field
because of their remarkable catalytic activity, gratifying stability, excellent selectivity, and …

The nitrogen cycle is one of the most important biogeochemical cycles on Earth because
nitrogen is an essential nutrient for all life forms. To supplement natural nitrogen fixation …

Conspectus One of the biggest challenges for humanity in the 21st century is easy access to
purified and potable water. The presence of pathogens and toxins in water causes more …

Metalloenzymes utilize inexpensive and earth-abundant transition metal ions as important
co-factors to enable binding of a dioxygen molecule so that it can be used in various …

The metallobiochemistry underlying the formation of the inorganic N–N-bond-containing
molecules nitrous oxide (N2O), dinitrogen (N2), and hydrazine (N2H4) is essential to the …

Biomimetic iron and manganese complexes have emerged as important catalysts in chemo-,
regio-, and stereoselective oxidation reactions. In this study, we describe a remote …

Highlights•Copper–oxygen complexes can effect difficult C–H oxidations in copper
monooxygenases.•The advancement of Cu–oxygen reactivity can contribute to societal …

Apart from its vital role as the terminal electron acceptor in oxidative phosphorylation in
nature, dioxygen also serves as a universal agent which diversifies natural products by …