The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …

Transition metal-catalyzed cross-coupling reactions of organic electrophiles and
organometallic reagents have emerged as a tremendously powerful synthetic tool, and the …

Chiral organoboronates have played a critical role in organic chemistry and in the
development of materials science and pharmaceuticals. Much effort has been devoted to …

The stereocontrolled construction of C− C bonds remains one of the foremost challenges in
organic synthesis. At the heart of any chemical synthesis of a natural product or designed …

This Review summarizes the advances in the construction of all-carbon quaternary
stereocenters via catalytic enantioselective desymmetrization of prochiral and meso …

Three-membered carbocycles are extremely important versatile building blocks for organic
chemistry. Their unique structural and electronic properties give rise to an array of very …

Cyclopropane skeletons play a prominent role in the development of organic synthesis and
pharmaceutical chemistry. Herein, we report the design and synthesis of a stable …

Non‐racemic chiral boronic esters are recognised as immensely valuable building blocks in
modern organic synthesis. Their stereospecific transformation into a variety of functional …

Cyclopropanes are structural motifs that are widely present in natural products and bioactive
molecules, and they are also tremendously useful building blocks in synthetic organic …

Conspectus Alkenes are versatile compounds that are readily available on a large scale
from industry or through organic synthesis. The widespread occurrence of alkenes provides …