Recent advances in gold (III) chemistry: structure, bonding, reactivity, and role in homogeneous catalysis
L Rocchigiani, M Bochmann - Chemical Reviews, 2020 - ACS Publications
Over the past decade the organometallic chemistry of gold (III) has seen remarkable
advances. This includes the synthesis of the first examples of several compound classes that …
advances. This includes the synthesis of the first examples of several compound classes that …
Migratory insertion of CO into a Au–C bond
A MeDalPhos-ligated gold (III) metallafluorene complex, generated via C–C oxidative
addition of biphenylene, reacts with CO to produce 9-fluorenone. Experimental and …
addition of biphenylene, reacts with CO to produce 9-fluorenone. Experimental and …
Valence Tautomerism Induced Proton Coupled Electron Transfer: X− H Bond Oxidation with a Dinuclear Au (II) Hydroxide Complex
KM Hess, IF Leach, L Wijtenhorst, H Lee… - Angewandte …, 2024 - Wiley Online Library
We report the preparation and characterization of the dinuclear AuII hydroxide complex
AuII2 (L) 2 (OH) 2 (L= N, N′‐bis (2, 6‐dimethyl) phenylformamidinate) and study its …
AuII2 (L) 2 (OH) 2 (L= N, N′‐bis (2, 6‐dimethyl) phenylformamidinate) and study its …
Highly Efficient Green Solution Processable Organic Light-Emitting Diodes Based on a Phosphorescent κ3-(N^C^C)Gold(III)-Alkynyl Complex
Gold (III) complexes are emerging as promising phosphorescent emitters for high-efficiency
organic light-emitting diodes (OLEDs). However, despite recent advances in the …
organic light-emitting diodes (OLEDs). However, despite recent advances in the …
Phosphorescent κ3‐(N^C^C)‐Gold(III) Complexes: Synthesis, Photophysics, Computational Studies and Application to Solution‐Processable OLEDs
Efficient OLED devices have been fabricated using organometallic complexes of platinum
group metals. Still, the high material cost and low stability represent central challenges for …
group metals. Still, the high material cost and low stability represent central challenges for …
Mechanistic Insights into C(sp2)−C(sp)N Reductive Elimination from Gold(III) Cyanide Complexes
A new family of phosphine‐ligated dicyanoarylgold (III) complexes has been prepared and
their reactivity towards reductive elimination has been studied in detail. Both, a highly …
their reactivity towards reductive elimination has been studied in detail. Both, a highly …
Synthesis of New Donor‐Substituted Biphenyls: Pre‐ligands for Highly Luminescent (C^ C^ D) Gold (III) Pincer Complexes
We herein report on new synthetic strategies for the preparation of pyridine and imidazole
substituted 2, 2'‐dihalo biphenyls. These structures are pre‐ligands suitable for the …
substituted 2, 2'‐dihalo biphenyls. These structures are pre‐ligands suitable for the …
Homolytic X‐H Bond Cleavage at a Gold (III) Hydroxide: Insights into One‐Electron Events at Gold
Abstract C (sp3)‐H and O− H bond breaking steps in the oxidation of 1, 4‐cyclohexadiene
and phenol by a Au (III)‐OH complex were studied computationally. The analysis reveals …
and phenol by a Au (III)‐OH complex were studied computationally. The analysis reveals …
Gold‐Catalyzed Alkoxy‐Carbonylation of Aryl and Vinyl Iodides
Herein, for the first time, we disclose the gold‐catalyzed alkoxy‐carbonylation of aryl and
vinyl iodides utilizing ligand‐enabled Au (I)/Au (III) redox catalysis. The present methodology …
vinyl iodides utilizing ligand‐enabled Au (I)/Au (III) redox catalysis. The present methodology …
(P^ N^ C) Ligands to Stabilize Gold (III): A Straightforward Access to Hydroxo, Formate, and Hydride Complexes
J Martín, J Schörgenhumer, M Biedrzycki… - Inorganic …, 2024 - ACS Publications
A novel class of (P^ N^ C) pincer ligands capable of stabilizing elusive gold (III) species is
reported here. Straightforward access to (P^ N^ C) gold (III) hydroxo, formate, and hydride …
reported here. Straightforward access to (P^ N^ C) gold (III) hydroxo, formate, and hydride …