Coinage Metal−N-Heterocyclic Carbene Complexes

JCY Lin, RTW Huang, CS Lee, A Bhattacharyya… - Chemical …, 2009 - ACS Publications
An N-heterocyclic carbene (NHC) contains a carbene carbon incorporated in a nitrogen-
containing heterocycle, presumably reactive and difficult to isolate. 1 The first isolation of …

Recent progress of d10 iodoargentate (I)/iodocuprate (I) hybrids: Structural diversity, directed synthesis, and photochromic/thermochromic properties

TL Yu, YM Guo, GX Wu, XF Yang, M Xue, YL Fu… - Coordination Chemistry …, 2019 - Elsevier
Abstract d 10 iodoargentates (I)/iodocuprates (I) are a family of organic-inorganic hybrids
with diverse structural topologies and fascinating photoelectric properties. Growing interest …

Functionalized imidazolium ionic liquids-modified chitosan materials: From synthesis approaches to applications

NF Alqahtani - Reactive and Functional Polymers, 2024 - Elsevier
Biodegradability, biocompatibility, and biological activity are just a few of the unique
qualities of chitosan, a biopolymer produced from chitin, that have garnered widespread …

Silver N-heterocyclic carbene complexes are potent uncompetitive inhibitors of the papain-like protease with antiviral activity against SARS-CoV-2

M Gil-Moles, C O'Beirne, IV Esarev… - RSC Medicinal …, 2023 - pubs.rsc.org
The ongoing SARS-CoV-2 pandemic has caused a high demand for novel innovative
antiviral drug candidates. Despite promising results, metal complexes have been relatively …

Organozirconium complexes as catalysts for Markovnikov-selective intermolecular hydrothiolation of terminal alkynes: scope and mechanism

CJ Weiss, TJ Marks - Journal of the American Chemical Society, 2010 - ACS Publications
The efficient and selective organozirconium (IV)-mediated, intermolecular hydrothiolation of
terminal alkynes by aliphatic, benzylic, and aromatic thiols using CGCZrMe2 (CGC …

Exploring the stability of the NHC–metal bond using thiones as probes

N Ségaud, C Johnson, A Farre… - Chemical Communications, 2021 - pubs.rsc.org
The metal–carbon bond in N-heterocyclic carbene (NHC) metal complexes, which are
ubiquitous in modern homogeneous catalysis, is often conjectured to be robust. Here …

[(NHC)(NHCewg)RuCl2(CHPh)] Complexes with Modified NHCewg Ligands for Efficient Ring‐Closing Metathesis Leading to Tetrasubstituted Olefins

V Sashuk, LH Peeck, H Plenio - Chemistry–A European …, 2010 - Wiley Online Library
Abstract Imidazolium salts (NHCewg⋅ HCl) with electronically variable substituents in the 4,
5‐position (H, H or Cl, Cl or H, NO2 or CN, CN) and sterically variable substituents in the 1, 3 …

N‐Heterocyclic Carbenes and Imidazole‐2‐thiones as Ligands for the Gold(I)‐Catalysed Hydroamination of Phenylacetylene

E Alvarado, AC Badaj, TG Larocque… - … –A European Journal, 2012 - Wiley Online Library
Abstract Gold (I) complexes of 1‐[1‐(2, 6‐dimethylphenylimino) alkyl]‐3‐(mesityl) imidazol‐2‐
ylidene (C^ ImineR), 1, 3‐dimesitylimidazol‐2‐ylidene (IMes) and of the corresponding …

N-heterocyclic carbene-amide rhodium (I) complexes: structures, dynamics, and catalysis

L Busetto, MC Cassani, C Femoni, M Mancinelli… - …, 2011 - ACS Publications
The amide-functionalized imidazolium salts [BocNHCH2CH2ImR] X (R= Me, X= I, 1a; R=
benzyl, X= Br, 1b; R= trityl, X= Cl, 1c) bearing increasingly bulky N-alkyl substituents were …

Highly 3, 4-selective living polymerization of isoprene and copolymerization with ε-caprolactone by an amidino N-heterocyclic carbene ligated lutetium bis (alkyl) …

C Yao, D Liu, P Li, C Wu, S Li, B Liu, D Cui - Organometallics, 2014 - ACS Publications
The amidino-modified N-heterocyclic carbene ligated lutetium bis (alkyl) complex 1,(Am-
NHC) Lu (CH2SiMe3) 2, was synthesized by treatment of (AmH-NHC-H) Br ((2, 6-i …