[HTML][HTML] Beyond U/Pu separation: Separation of americium from the highly active PUREX raffinate

P Zsabka, A Wilden, K Van Hecke, G Modolo… - Journal of nuclear …, 2023 - Elsevier
This review provides a comprehensive overview of published hydrometallurgical chemical
processes capable of separating americium from curium and the lanthanides. A search for …

An overview of solvent extraction processes developed in Europe for advanced nuclear fuel recycling, part 1—heterogeneous recycling

A Geist, JM Adnet, S Bourg, C Ekberg… - Separation science …, 2021 - Taylor & Francis
The hydrometallurgical separation concepts for the heterogeneous recycling of irradiated
nuclear fuel developed in Europe are presented and discussed. Most of these concepts …

Solvent extraction systems for mutual separation of Am (III) and Cm (III) from nitric acid solutions. A review of recent state-of-the-art

P Matveev, PK Mohapatra, SN Kalmykov… - Solvent Extraction and …, 2021 - Taylor & Francis
Americium and curium, present in spent nuclear fuel, are carried forward to the high-level
wastes (HLW) upon its reprocessing within the closed nuclear fuel cycle strategy. These …

Engineering lanmodulin's selectivity for actinides over lanthanides by controlling solvent coordination and second-sphere interactions

JA Mattocks, JA Cotruvo, GJP Deblonde - Chemical Science, 2022 - pubs.rsc.org
Develo** chelators that combine high affinity and selectivity for lanthanides and/or
actinides is paramount for numerous industries, including rare earths mining, nuclear waste …

Synchrotron radiation techniques and their application to actinide materials

R Caciuffo, GH Lander, G van der Laan - Reviews of Modern Physics, 2023 - APS
Research on actinide materials, both basic and applied, has been greatly advanced by the
general techniques available from high-intensity photon beams from x-ray synchrotron …

Remarkable Improvement in Am3+ and Cm3+ Separation Using a Cooperative Counter Selectivity Strategy by a Combination of Branched Diglycolamides and …

RB Gujar, AS Kanekar, A Bhattacharyya… - Inorganic …, 2024 - ACS Publications
Separation of Am3+ and Cm3+ is one of the most challenging problems in the back-end of
the nuclear fuel cycle. In the present work, we exploited the cooperative effect of the …

Americium recovery from highly active PUREX raffinate by solvent extraction: the EXAm process. A review of 10 years of R&D

M Miguirditchian, V Vanel, C Marie… - … Extraction and Ion …, 2020 - Taylor & Francis
In the framework of the R&D program conducted in France on partitioning and transmutation
of minor actinides, a solvent extraction process was developed for separating americium …

[HTML][HTML] Uncovering the inverse relationship between Am/Eu separation capability and softness of N-heterocyclic carboxylate ligands

PW Huang, CZ Wang, Z Su, DX Jiang, JL Wang… - Supramolecular …, 2025 - Elsevier
In the advanced spent fuel wet reprocessing process, mutual separation of trivalent actinide
ions (An 3+) and lanthanide ions (Ln 3+) is extremely challenging. The development of back …

Uncovering heavy actinide covalency: implications for minor actinide partitioning

A Chandrasekar, TK Ghanty - Inorganic chemistry, 2019 - ACS Publications
Across the actinide period, the stability of the trivalent oxidation state predominates in the
heavy actinides, making their chemical nature close to that of rare earth elements. The …
E Mossini, E Macerata, N Boubals… - Industrial & …, 2021 - ACS Publications
Recovery of trivalent minor actinides or of the transuranium elements from highly active
raffinate could be industrially achieved by innovative Selective ActiNide EXtraction (i …