Deciphering structure and aggregation in asphaltenes: hypothesis-driven design and development of synthetic model compounds

DE Scott, M Schulze, JM Stryker… - Chemical Society …, 2021 - pubs.rsc.org
Asphaltenes comprise the heaviest and least understood fraction of crude petroleum. The
asphaltenes are a diverse and complex mixture of organic and organometallic molecules in …

Nanotechnology applied to thermal enhanced oil recovery processes: A review

OE Medina, C Olmos, SH Lopera, FB Cortés… - Energies, 2019 - mdpi.com
The increasing demand for fossil fuels and the depleting of light crude oil in the next years
generates the need to exploit heavy and unconventional crude oils. To face this challenge …

Advances in asphaltene petroleomics. part 1: asphaltenes are composed of abundant island and archipelago structural motifs

ML Chacón-Patiño, SM Rowland, RP Rodgers - Energy & fuels, 2017 - ACS Publications
For decades, discussion of asphaltene structure focused primarily on molecular weight. Now
that it is widely accepted that asphaltene monomers are between∼ 250 and 1200 g/mol …

Overview of asphaltene nanostructures and thermodynamic applications

B Schuler, Y Zhang, F Liu, AE Pomerantz… - Energy & …, 2020 - ACS Publications
Previously, asphaltene science had been hindered by many significant uncertainties
regarding molecular weight, molecular structure, and nanocolloidal characteristics in …

Advances in asphaltene petroleomics. Part 3. Dominance of island or archipelago structural motif is sample dependent

ML Chacón-Patiño, SM Rowland, RP Rodgers - Energy & Fuels, 2018 - ACS Publications
Asphaltene structure is one of the most controversial topics in petroleum chemistry. The
controversy is centered on the organization of aromatic cores within asphaltene molecules …

Advances in asphaltene petroleomics. Part 2: selective separation method that reveals fractions enriched in island and archipelago structural motifs by mass …

ML Chacón-Patiño, SM Rowland, RP Rodgers - Energy & fuels, 2018 - ACS Publications
Advances in high-resolution Fourier transform ion cyclotron resonance mass spectrometry
(FT-ICR MS) enable molecular-level characterization of ultracomplex asphaltene samples …

Analyzing properties of model asphalts using molecular simulation

L Zhang, ML Greenfield - Energy & fuels, 2007 - ACS Publications
Molecular simulations have been used to estimate the properties of three-component
mixtures whose constituents were chosen to represent the chemical families found in paving …

The influence of asphaltene-resin molecular interactions on the colloidal stability of crude oil

M Mousavi, T Abdollahi, F Pahlavan, EH Fini - Fuel, 2016 - Elsevier
In the colloidal hypothesis of vacuum residua and asphalt, micelles are assumed to have an
asphaltenic core with the greatest weight and aromaticity and an outer shell composed of …

Heavy petroleum composition. 3. Asphaltene aggregation

AM McKenna, LJ Donald, JE Fitzsimmons, P Juyal… - Energy & …, 2013 - ACS Publications
Molecular characterization of asphaltenes by conventional analytical techniques is a
challenge because of their compositional complexity, high heteroatom content, and …

Heavy petroleum composition. 5. Compositional and structural continuum of petroleum revealed

DC Podgorski, YE Corilo, L Nyadong, VV Lobodin… - Energy & …, 2013 - ACS Publications
Twenty-five years ago, Boduszynski et al. conducted a comprehensive study of heavy oil
composition and concluded that crude oil composition increases gradually and continuously …