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Tuning redox activity in metal–organic frameworks: From structure to application
Among the various characteristics of metal–organic frameworks (MOFs), redox activity, the
ability to store or release electrons is a vital property for functional MOFs in applications like …
ability to store or release electrons is a vital property for functional MOFs in applications like …
A review for Metal-Organic Frameworks (MOFs) utilization in capture and conversion of carbon dioxide into valuable products
Carbon dioxide (CO 2) has become a primary atmospheric greenhouse gas that has stirred
up numerous energies and environmental-related mishaps around the world. Its unwelcome …
up numerous energies and environmental-related mishaps around the world. Its unwelcome …
Coordination Defect‐Induced Frustrated Lewis Pairs in Polyoxo‐metalate‐Based Metal–Organic Frameworks for Efficient Catalytic Hydrogenation
Y Liang, Z Zhang, X Su, X Feng, S **ng… - Angewandte …, 2023 - Wiley Online Library
Precise control of the structure and spatial distance of Lewis acid (LA) and Lewis base (LB)
sites in a porous system to construct efficient solid frustrated Lewis pair (FLP) catalyst is vital …
sites in a porous system to construct efficient solid frustrated Lewis pair (FLP) catalyst is vital …
Molecular scalpel to chemically cleave metal–organic frameworks for induced phase transition
A bottom-up chemical synthesis of metal–organic frameworks (MOFs) permits significant
structural diversity because of various combinations of metal centers and different organic …
structural diversity because of various combinations of metal centers and different organic …
Copper Nanocrystals Encapsulated in Zr-based Metal–Organic Frameworks for Highly Selective CO2 Hydrogenation to Methanol
We show that the activity and selectivity of Cu catalyst can be promoted by a Zr-based metal–
organic framework (MOF), Zr6O4 (OH) 4 (BDC) 6 (BDC= 1, 4-benzenedicarboxylate), UiO …
organic framework (MOF), Zr6O4 (OH) 4 (BDC) 6 (BDC= 1, 4-benzenedicarboxylate), UiO …
Dynamic Restructuring of Coordinatively Unsaturated Copper Paddle Wheel Clusters to Boost Electrochemical CO2 Reduction to Hydrocarbons**
The electrochemical reduction of CO2 to hydrocarbons involves a multistep proton‐coupled
electron transfer (PCET) reaction. Second coordination sphere engineering is reported to be …
electron transfer (PCET) reaction. Second coordination sphere engineering is reported to be …
Electronic properties of bimetallic metal–organic frameworks (MOFs): tailoring the density of electronic states through MOF modularity
EA Dolgopolova, AJ Brandt… - Journal of the …, 2017 - ACS Publications
The development of porous well-defined hybrid materials (eg, metal–organic frameworks or
MOFs) will add a new dimension to a wide number of applications ranging from …
MOFs) will add a new dimension to a wide number of applications ranging from …
Stimuli-modulated metal oxidation states in photochromic MOFs
Tuning metal oxidation states in metal–organic framework (MOF) nodes by switching
between two discrete linker photoisomers via an external stimulus was probed for the first …
between two discrete linker photoisomers via an external stimulus was probed for the first …
Tailoring metal-organic frameworks-based nanozymes for bacterial theranostics
Nanozymes are next-generation artificial enzymes having distinguished features such as
cost-effective, enhanced surface area, and high stability. However, limited selectivity and …
cost-effective, enhanced surface area, and high stability. However, limited selectivity and …
Structure, characterization, and catalytic properties of open-metal sites in metal organic frameworks
Metal organic framework materials (MOFs) offer a unique opportunity for investigating active
sites that have either previously not been studied from a catalytic standpoint or have only …
sites that have either previously not been studied from a catalytic standpoint or have only …