Tuning redox activity in metal–organic frameworks: From structure to application

SAA Razavi, W Chen, HC Zhou, A Morsali - Coordination Chemistry …, 2024 - Elsevier
Among the various characteristics of metal–organic frameworks (MOFs), redox activity, the
ability to store or release electrons is a vital property for functional MOFs in applications like …

A review for Metal-Organic Frameworks (MOFs) utilization in capture and conversion of carbon dioxide into valuable products

FN Al-Rowaili, U Zahid, S Onaizi, M Khaled… - Journal of CO2 …, 2021 - Elsevier
Carbon dioxide (CO 2) has become a primary atmospheric greenhouse gas that has stirred
up numerous energies and environmental-related mishaps around the world. Its unwelcome …

Coordination Defect‐Induced Frustrated Lewis Pairs in Polyoxo‐metalate‐Based Metal–Organic Frameworks for Efficient Catalytic Hydrogenation

Y Liang, Z Zhang, X Su, X Feng, S **ng… - Angewandte …, 2023 - Wiley Online Library
Precise control of the structure and spatial distance of Lewis acid (LA) and Lewis base (LB)
sites in a porous system to construct efficient solid frustrated Lewis pair (FLP) catalyst is vital …

Molecular scalpel to chemically cleave metal–organic frameworks for induced phase transition

X Zhou, J Dong, Y Zhu, L Liu, Y Jiao, H Li… - Journal of the …, 2021 - ACS Publications
A bottom-up chemical synthesis of metal–organic frameworks (MOFs) permits significant
structural diversity because of various combinations of metal centers and different organic …

Copper Nanocrystals Encapsulated in Zr-based Metal–Organic Frameworks for Highly Selective CO2 Hydrogenation to Methanol

B Rungtaweevoranit, J Baek, JR Araujo… - Nano …, 2016 - ACS Publications
We show that the activity and selectivity of Cu catalyst can be promoted by a Zr-based metal–
organic framework (MOF), Zr6O4 (OH) 4 (BDC) 6 (BDC= 1, 4-benzenedicarboxylate), UiO …

Dynamic Restructuring of Coordinatively Unsaturated Copper Paddle Wheel Clusters to Boost Electrochemical CO2 Reduction to Hydrocarbons**

W Zhang, C Huang, J Zhu, Q Zhou, R Yu… - Angewandte Chemie …, 2022 - Wiley Online Library
The electrochemical reduction of CO2 to hydrocarbons involves a multistep proton‐coupled
electron transfer (PCET) reaction. Second coordination sphere engineering is reported to be …

Electronic properties of bimetallic metal–organic frameworks (MOFs): tailoring the density of electronic states through MOF modularity

EA Dolgopolova, AJ Brandt… - Journal of the …, 2017 - ACS Publications
The development of porous well-defined hybrid materials (eg, metal–organic frameworks or
MOFs) will add a new dimension to a wide number of applications ranging from …

Stimuli-modulated metal oxidation states in photochromic MOFs

CR Martin, KC Park, GA Leith, J Yu… - Journal of the …, 2022 - ACS Publications
Tuning metal oxidation states in metal–organic framework (MOF) nodes by switching
between two discrete linker photoisomers via an external stimulus was probed for the first …

Tailoring metal-organic frameworks-based nanozymes for bacterial theranostics

A Ali, M Ovais, H Zhou, Y Rui, C Chen - Biomaterials, 2021 - Elsevier
Nanozymes are next-generation artificial enzymes having distinguished features such as
cost-effective, enhanced surface area, and high stability. However, limited selectivity and …

Structure, characterization, and catalytic properties of open-metal sites in metal organic frameworks

JN Hall, P Bollini - Reaction Chemistry & Engineering, 2019 - pubs.rsc.org
Metal organic framework materials (MOFs) offer a unique opportunity for investigating active
sites that have either previously not been studied from a catalytic standpoint or have only …