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Electrolyte and electrode designs for enhanced ion transport properties to enable high performance lithium batteries
Lithium-ion batteries (LiBs) are recognized as the most rapidly growing energy storage
technology. To improve the energy and power density of LiBs, tremendous progress has …
technology. To improve the energy and power density of LiBs, tremendous progress has …
Toward bottom-up understanding of transport in concentrated battery electrolytes
Bottom-up understanding of transport describes how molecular changes alter species
concentrations and electrolyte voltage drops in operating batteries. Such an understanding …
concentrations and electrolyte voltage drops in operating batteries. Such an understanding …
Experimental platform for determining the maximum limiting current in a polymer electrolyte
The applicability of both solid and liquid electrolytes in practical batteries is governed by
limiting current. The limiting current for lithium-ion transport in a polymer electrolyte was …
limiting current. The limiting current for lithium-ion transport in a polymer electrolyte was …
Concentration and velocity profiles in a polymeric lithium-ion battery electrolyte
Predictive knowledge of ion transport in electrolytes which bridges microscopic and
macroscopic length scales is imperative to design new ion conductors and to simulate …
macroscopic length scales is imperative to design new ion conductors and to simulate …
Characterizing ion transport in electrolytes via concentration and velocity profiles
Current flowing through an electrolyte is accompanied by continuum motion of ions and
solvent, species concentration profiles, and the electric field. While, historically, the …
solvent, species concentration profiles, and the electric field. While, historically, the …
Overdetermination method for accurate dynamic ion correlations in highly concentrated electrolytes
T Pothmann, M Middendorf, C Gerken… - Faraday …, 2024 - pubs.rsc.org
Highly concentrated battery electrolytes exhibit a low flammability as well as a high thermal
and electrochemical stability, and they typically form stable solid electrolyte interphases in …
and electrochemical stability, and they typically form stable solid electrolyte interphases in …
Inaccessible polarization-induced phase transitions in a block copolymer electrolyte: An unconventional mechanism for the limiting current
Block copolymer electrolytes that microphase separate into mechanically rigid and ion-
conducting domains are promising materials for lithium metal batteries. We present …
conducting domains are promising materials for lithium metal batteries. We present …
Practical considerations for enabling Li| polymer electrolyte batteries
Rechargeable lithium metal batteries (LMBs) hold promise to deliver high energy densities,
but their commercial application is hampered by challenges such as inhomogeneous lithium …
but their commercial application is hampered by challenges such as inhomogeneous lithium …
Limiting current in nanostructured block copolymer electrolytes
Next-generation electrolytes for lithium batteries must be able to conduct ions at sufficiently
high current densities; yet this regime is rarely studied directly. The limiting current density of …
high current densities; yet this regime is rarely studied directly. The limiting current density of …
Tomographic X-ray particle tracking velocimetry: Proof-of-concept in a cree** flow
We investigate the feasibility of in-laboratory tomographic X-ray particle tracking velocimetry
(TXPTV) and consider cree** flows with nearly density matched flow tracers. Specifically …
(TXPTV) and consider cree** flows with nearly density matched flow tracers. Specifically …