Reactions in single-molecule junctions

H Chen, C Jia, X Zhu, C Yang, X Guo… - Nature Reviews …, 2023 - nature.com
Develo** new materials is a long-standing goal that extends across the fields of synthesis,
catalysis, nanotechnology and materials science. Transforming one compound or material …

Single-molecule junction: A reliable platform for monitoring molecular physical and chemical processes

X **e, P Li, Y Xu, L Zhou, Y Yan, L **e, C Jia, X Guo - ACS nano, 2022 - ACS Publications
Monitoring and manipulating the physical and chemical behavior of single molecules is an
important development direction of molecular electronics that aids in understanding the …

Boosting the performance of single-atom catalysts via external electric field polarization

Y Pan, X Wang, W Zhang, L Tang, Z Mu, C Liu… - Nature …, 2022 - nature.com
Single-atom catalysts represent a unique catalytic system with high atomic utilization and
tunable reaction pathway. Despite current successes in their optimization and tailoring …

Electric-field mediated chemistry: uncovering and exploiting the potential of (oriented) electric fields to exert chemical catalysis and reaction control

S Shaik, D Danovich, J Joy, Z Wang… - Journal of the American …, 2020 - ACS Publications
This Perspective discusses oriented external-electric-fields (OEEF), and other electric-field
types, as “smart reagents”, which enable in principle control over wide-ranging aspects of …

High electric fields on water microdroplets catalyze spontaneous and fast reactions in halogen-bond complexes

C Zhu, LN Pham, X Yuan, H Ouyang… - Journal of the …, 2023 - ACS Publications
The use of external electric fields as green and efficient catalysts in synthetic chemistry has
recently received significant attention for their ability to deliver remarkable control of reaction …

Electric fields in catalysis: From enzymes to molecular catalysts

NG Léonard, R Dhaoui, T Chantarojsiri, JY Yang - ACS catalysis, 2021 - ACS Publications
Electric fields underlie all reactions and impact reactivity by interacting with the dipoles and
net charges of transition states, products, and reactants to modify the free energy landscape …

Selectivity in single-molecule reactions by tip-induced redox chemistry

F Albrecht, S Fatayer, I Pozo, I Tavernelli, J Repp… - Science, 2022 - science.org
Controlling selectivity of reactions is an ongoing quest in chemistry. In this work, we
demonstrate reversible and selective bond formation and dissociation promoted by tip …

Oriented Electrostatic Effects on O2 and CO2 Reduction by a Polycationic Iron Porphyrin

DJ Martin, JM Mayer - Journal of the American Chemical Society, 2021 - ACS Publications
Next-generation energy technologies require improved methods for rapid and efficient
chemical-to-electrical energy transformations. One new approach has been to include …

Advances in single-molecule junctions as tools for chemical and biochemical analysis

EM Dief, PJ Low, I Díez-Pérez, N Darwish - Nature Chemistry, 2023 - nature.com
The development of miniaturized electronics has led to the design and construction of
powerful experimental platforms capable of measuring electronic properties to the level of …

Electric field–induced selective catalysis of single-molecule reaction

X Huang, C Tang, J Li, LC Chen, J Zheng, P Zhang… - Science …, 2019 - science.org
Oriented external electric fields (OEEFs) offer a unique chance to tune catalytic selectivity by
orienting the alignment of the electric field along the axis of the activated bond for a specific …