Reactions in single-molecule junctions
Develo** new materials is a long-standing goal that extends across the fields of synthesis,
catalysis, nanotechnology and materials science. Transforming one compound or material …
catalysis, nanotechnology and materials science. Transforming one compound or material …
Single-molecule junction: A reliable platform for monitoring molecular physical and chemical processes
Monitoring and manipulating the physical and chemical behavior of single molecules is an
important development direction of molecular electronics that aids in understanding the …
important development direction of molecular electronics that aids in understanding the …
Boosting the performance of single-atom catalysts via external electric field polarization
Y Pan, X Wang, W Zhang, L Tang, Z Mu, C Liu… - Nature …, 2022 - nature.com
Single-atom catalysts represent a unique catalytic system with high atomic utilization and
tunable reaction pathway. Despite current successes in their optimization and tailoring …
tunable reaction pathway. Despite current successes in their optimization and tailoring …
Electric-field mediated chemistry: uncovering and exploiting the potential of (oriented) electric fields to exert chemical catalysis and reaction control
This Perspective discusses oriented external-electric-fields (OEEF), and other electric-field
types, as “smart reagents”, which enable in principle control over wide-ranging aspects of …
types, as “smart reagents”, which enable in principle control over wide-ranging aspects of …
High electric fields on water microdroplets catalyze spontaneous and fast reactions in halogen-bond complexes
C Zhu, LN Pham, X Yuan, H Ouyang… - Journal of the …, 2023 - ACS Publications
The use of external electric fields as green and efficient catalysts in synthetic chemistry has
recently received significant attention for their ability to deliver remarkable control of reaction …
recently received significant attention for their ability to deliver remarkable control of reaction …
Electric fields in catalysis: From enzymes to molecular catalysts
Electric fields underlie all reactions and impact reactivity by interacting with the dipoles and
net charges of transition states, products, and reactants to modify the free energy landscape …
net charges of transition states, products, and reactants to modify the free energy landscape …
Selectivity in single-molecule reactions by tip-induced redox chemistry
Controlling selectivity of reactions is an ongoing quest in chemistry. In this work, we
demonstrate reversible and selective bond formation and dissociation promoted by tip …
demonstrate reversible and selective bond formation and dissociation promoted by tip …
Oriented Electrostatic Effects on O2 and CO2 Reduction by a Polycationic Iron Porphyrin
DJ Martin, JM Mayer - Journal of the American Chemical Society, 2021 - ACS Publications
Next-generation energy technologies require improved methods for rapid and efficient
chemical-to-electrical energy transformations. One new approach has been to include …
chemical-to-electrical energy transformations. One new approach has been to include …
Advances in single-molecule junctions as tools for chemical and biochemical analysis
The development of miniaturized electronics has led to the design and construction of
powerful experimental platforms capable of measuring electronic properties to the level of …
powerful experimental platforms capable of measuring electronic properties to the level of …
Electric field–induced selective catalysis of single-molecule reaction
Oriented external electric fields (OEEFs) offer a unique chance to tune catalytic selectivity by
orienting the alignment of the electric field along the axis of the activated bond for a specific …
orienting the alignment of the electric field along the axis of the activated bond for a specific …