SABRE: Chemical kinetics and spin dynamics of the formation of hyperpolarization

DA Barskiy, S Knecht, AV Yurkovskaya… - Progress in Nuclear …, 2019 - Elsevier
In this review, we present the physical principles of the SABRE (Signal Amplification By
Reversible Exchange) method. SABRE is a promising hyperpolarization technique that …

Recent advances in the application of parahydrogen in catalysis and biochemistry

G Buntkowsky, F Theiss, J Lins, YA Miloslavina… - RSC …, 2022 - pubs.rsc.org
Nuclear Magnetic Resonance (NMR) spectroscopy and Magnetic Resonance Imaging (MRI)
are analytical and diagnostic tools that are essential for a very broad field of applications …

In Vivo Metabolic Imaging of [1‐13C]Pyruvate‐d3 Hyperpolarized By Reversible Exchange With Parahydrogen**

H de Maissin, PR Groß, O Mohiuddin… - Angewandte Chemie …, 2023 - Wiley Online Library
Metabolic magnetic resonance imaging (MRI) using hyperpolarized (HP) pyruvate is
becoming a non‐invasive technique for diagnosing, staging, and monitoring response to …

Over 20% carbon-13 polarization of perdeuterated pyruvate using reversible exchange with parahydrogen and spin-lock induced crossing at 50 μT

AB Schmidt, J Eills, L Dagys, M Gierse… - The Journal of …, 2023 - ACS Publications
Carbon-13 hyperpolarized pyruvate is about to become the next-generation contrast agent
for molecular magnetic resonance imaging of cancer and other diseases. Here, efficient and …

LIGHT-SABRE Hyperpolarizes 1-13C-Pyruvate Continuously without Magnetic Field Cycling

AN Pravdivtsev, K Buckenmaier, N Kempf… - The Journal of …, 2023 - ACS Publications
Nuclear spin hyperpolarization enables real-time observation of metabolism and
intermolecular interactions in vivo. 1-13C-pyruvate is the leading hyperpolarized tracer …

In Situ Hyperpolarization Enables 15N and 13C Benchtop NMR at Natural Isotopic Abundance

R Kircher, J Xu, DA Barskiy - Journal of the American Chemical …, 2023 - ACS Publications
Without employing isotopic labeling, we demonstrate the generation of 15N and 13C NMR
signals for molecules containing− NH2 motifs using benchtop NMR spectrometers (1–1.4 T) …

Parahydrogen-based NMR signal amplification by reversible exchange (SABRE): Recent advances and applications

OG Salnikov, DB Burueva, IV Skovpin… - Mendeleev …, 2023 - Elsevier
Signal amplification by reversible exchange (SABRE) is a rapidly develo** nuclear
magnetic resonance (NMR) hyperpolarization technique utilizing parahydrogen for dramatic …

Synergies between hyperpolarized NMR and microfluidics: A review

J Eills, W Hale, M Utz - Progress in Nuclear Magnetic Resonance …, 2022 - Elsevier
Hyperpolarized nuclear magnetic resonance and lab-on-a-chip microfluidics are two
dynamic, but until recently quite distinct, fields of research. Recent developments in both …

13C MRI of hyperpolarized pyruvate at 120 µT

N Kempf, R Körber, M Plaumann, AN Pravdivtsev… - Scientific Reports, 2024 - nature.com
Nuclear spin hyperpolarization increases the sensitivity of magnetic resonance dramatically,
enabling many new applications, including real-time metabolic imaging. Parahydrogen …

Improving SABRE hyperpolarization with highly nonintuitive pulse sequences: Moving beyond avoided crossings to describe dynamics

SL Eriksson, JR Lindale, X Li, WS Warren - Science Advances, 2022 - science.org
Signal amplification by reversible exchange (SABRE) creates “hyperpolarization”(large spin
magnetization) using a transition metal catalyst and parahydrogen, addressing the …