Polyoxometalates (POMs) are composed of cations and polyanion clusters 1 with structural
diversity, in which the oxometal polyhedra of MOx (x= 5, 6) are the basic construction units …

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Enzymatic stereoselectivity has typically been unrivalled by most chemical catalysts,
especially in the conversion of small substrates. According to the 'lock-and-key theory' …

Catalytic asymmetric synthesis has been one of the most active research areas in chemistry
(Nobel Prize in 2001). The development of efficient chiral catalysts plays a crucial role in …

A continuous flow cascade of multi-step catalytic reactions is a cutting-edge concept to
revolutionize stepwise catalytic synthesis yet is still challenging in practical applications …

Catalytic asymmetric cyanations of prochiral unsaturated compounds affording the
corresponding nitrile products in high enantiomeric excess (≥ 90% in general) are …

Chiral tertiary alcohols are an important class of organic compounds which have found wide
applications in both academia and industry. Therefore, various synthetic strategies towards …

The evolution of zinc-based metal-organic frameworks (MOFs) materials exhibits fascinating
characteristics for precise chemical transformations. Among various MOFs, divalent metal …

Polyoxometalates (POMs) as efficient catalysts can be used a wide range of chemical
transformations due to their tunable Brønsted/Lewis-acidity and redox properties. Herein, we …

A general and practical strategy for remote site‐selective functionalization of unactivated
aliphatic C− H bonds in various amides by radical chemistry is introduced. C− H bond …