Over the past decade, the landscape of molecular synthesis has gained major impetus by
the introduction of late-stage functionalization (LSF) methodologies. C–H functionalization …

The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …

Nitrogen (N) is ubiquitously found in bioactive molecules, pharmaceutical agents, and
organic functional materials. Accordingly, development of new C–N bond-forming catalysis …

Transition-metal-catalyzed C–H bond functionalizations have had an enormous influence on
organic synthesis in recent times. However, the use of low-abundance 4d and 5d metals is …

Rhodium (Rh) acylnitrene complexes are widely implicated in catalytic C–H amidation
reactions but have eluded isolation and structural characterization. To overcome this …

Catalytic transformation of ubiquitous C–H bonds into valuable C–N bonds offers an efficient
synthetic approach to construct N-functionalized molecules. Over the last few decades …

Conspectus Catalytic reactions that construct carbon–nitrogen bonds are one of central
themes in both synthetic and medicinal chemistry since the obtainable nitrogen-containing …

Organic reactions that involve the direct functionalization of non-activated C–H bonds
represent an attractive class of transformations which maximize atom-and step-economy …

A key aspect of bacterial survival is the ability to evolve while migrating across spatially
varying environmental challenges. Laboratory experiments, however, often study evolution …

Enantioselective transition metal catalysis is an area very much at the forefront of
contemporary synthetic research. The development of processes that enable the efficient …