Metal-free phosphonation of heteroarene N-oxides with trialkyl phosphite at room temperature

MT Chen, X You, LG Bai, QL Luo - Organic & Biomolecular Chemistry, 2017 - pubs.rsc.org
A new protocol is described for the conversion of heteroarene N-oxides to
heteroarylphosphonates through in situ activation with bromotrichloromethane. The N …

A Facile Synthetic Method for Anhydride from Carboxylic Acid with the Promotion of Triphenylphosphine Oxide and Oxaloyl Chloride

M Lu, H Fan, Q Liu, X Sun - ACS omega, 2022 - ACS Publications
A highly efficient synthesis reaction of carboxylic anhydrides catalyzed by
triphenylphosphine oxide is described for the quick synthesis of a range of symmetric …

[HTML][HTML] Hydrogenation of alkenes with NaBH4, CH3CO2H, Pd/C in the presence of O-and N-benzyl functions

N Al Soom, T Thiemann - International Journal of Organic Chemistry, 2016 - scirp.org
NaBH4, CH3CO2H, Pd/C has been described as an effective reagent system to
hydrogenate alkenes. Here, we show that the hydrogenation occurs chemoselectively …

[HTML][HTML] Our experience of using thermally recycled silica gel in a teaching and small research laboratory setting

FS Wahshi, MD Alqahtani, M Abdulla, A Al-Hemyari… - Proceedings, 2018 - mdpi.com
Organic synthetic research laboratories generate a large amount of waste. Some of the
waste is the silica gel used as the stationary phase in column chromatographic separations …

From allenes to spirobifluorenes: on the way to device-compatible chiroptical systems

A Ozcelik, R Pereira-Cameselle… - Current Organic …, 2020 - ingentaconnect.com
The last decade has seen a huge growth in the construction of chiral systems to expand the
scope of chiroptical applications. Dependence of chiroptical response on molecular …

One-pot synthesis of cinnamic anhydrides from cinnamic acids and 6-chloro-2,4-dimethoxy-sec-triazine (CDMT) at room temperature

GCE Raja, Y Son, M Kim, S Lee, J Oh - Synthetic Communications, 2017 - Taylor & Francis
Symmetric cinnamic anhydrides were prepared by the reactions of cinnamic acid substrates
with 6-chloro-2, 4-dimethoxy-sec-triazine. The reactions were performed at room …

Synthesis of 4′-Alkoxy-4-(ω-cinnamoylalkoxy) azobenzenes and Their Photoswitchable Behavior

A Al-Hemyari, M Bufaroosha, T Thiemann - Chemistry Proceedings, 2021 - mdpi.com
In search of new thermotropic, photoswitchable materials, a number of 4′-alkoxy-4-(ω-
cinnamoylalkoxy) azobenzenes were prepared. The synthetic procedure included O …

[PDF][PDF] Deuteration of alkenes with NaBD4/AcOD in pre-sence of Pd on carbon

F AlJunaibi, H Aldhanhani… - Multidisciplinary …, 2019 - pdfs.semanticscholar.org
Activated alkenes such as cinnamates and chalcones can easily be converted to 2, 3-
dideuterio-arylpropionates and dideuteriochalcones, respectively, by the action of NaBD4 …

[HTML][HTML] Synthesis New of Nucleoside of 1,3-bis-(2,3,5-tri-O-Benzoyl-β-d-Ribofuranosyl)-8-(Trifluoromethyl)-2-Methyl-4-Quinazolinone

LM Break, WS Al-harthi - Proceedings, 2018 - mdpi.com
Fluorinated nucleosides are very important for increased biological and chemical stability of
organ fluorine compounds. Synthesis of (1H)-8-trifluloromethyl-2-methyl-4-quinazolinone 3 …

[PDF][PDF] Use of triphenylphosphine-bromotrichloromethane (PPh3-BrCCl3) in the preparation of acylhydrazines, N-methylamides, anilides and N-arylmaleimides from …

A Al-Hemyari, A Hashim… - Multidisciplinary …, 2019 - pdfs.semanticscholar.org
In certain countries, many of the reagents used to transform carboxylic acids to acyl halides
such as phosphorus trichloride, phosphorus tribromide, phosphorus pentachloride …