Organic thermally activated delayed fluorescence (TADF) compounds used in photocatalysis

MA Bryden, E Zysman-Colman - Chemical Society Reviews, 2021 - pubs.rsc.org
Organic compounds that show Thermally Activated Delayed Fluorescence (TADF) have
become wildly popular as next-generation emitters in organic light emitting diodes (OLEDs) …

Transition metal-catalysed allylic functionalization reactions involving radicals

HM Huang, P Bellotti, F Glorius - Chemical Society Reviews, 2020 - pubs.rsc.org
Transition metal-catalysed allylic functionalization reactions have been established as a
central synthetic transformation to enable the construction of carbon–carbon and carbon …

4CzIPN-tBu-Catalyzed Proton-Coupled Electron Transfer for Photosynthesis of Phosphorylated N-Heteroaromatics

Y Liu, XL Chen, XY Li, SS Zhu, SJ Li… - Journal of the …, 2020 - ACS Publications
2, 4, 5, 6-Tetrakis (3, 6-di-tert-butyl-9 H-carbazol-9-yl) isophthalonitrile (4CzIPN-t Bu) was
developed as a photocatalyst for the phosphorus-radical-initiated cascade cyclization …

Exploiting photoredox catalysis for carbohydrate modification through C–H and C–C bond activation

A Shatskiy, EV Stepanova, MD Kärkäs - Nature Reviews Chemistry, 2022 - nature.com
Photoredox catalysis has recently emerged as a powerful synthetic platform for accessing
complex chemical structures through non-traditional bond disconnection strategies that …

Investigating Oxidative Addition Mechanisms of Allylic Electrophiles with Low-Valent Ni/Co Catalysts Using Electroanalytical and Data Science Techniques

T Tang, E Jones, T Wild, A Hazra… - Journal of the …, 2022 - ACS Publications
The catalysis by a π-allyl-Co/Ni complex has drawn significant attention recently due to its
distinct reactivity in reductive Co/Ni-catalyzed allylation reactions. Despite significant …

Recent Advances and Development in Visible‐Light‐Mediated Glycosylation: An Expanding Research Area in Glycochemistry

Z Azeem, P Kumar Mandal - Advanced Synthesis & Catalysis, 2023 - Wiley Online Library
In the last fifteen years, the development of visible‐light photocatalysis, metal/photoredox
dual catalysis has become the forefront as a new paradigm in organic synthesis as well as in …

Regioselective Formal β‐Allylation of Carbonyl Compounds Enabled by Cooperative Nickel and Photoredox Catalysis

K Liu, Z Wang, AN Künzel, M Layh… - Angewandte …, 2023 - Wiley Online Library
Abstract The Tsuji–Trost reaction between carbonyl compounds and allylic precursors has
been widely used in the synthesis of natural products and pharmaceutical compounds. As …

Stereoselective Three-Component Allylic Alkylation Enabled by Dual Photoredox/Ni Catalysis

Q Zeng, F Gao, J Benet-Buchholz, AW Kleij - ACS Catalysis, 2023 - ACS Publications
A modular and practical approach has been developed for the stereoselective formation of
elaborate allylic alcohols through a three-component reaction (3CR) between vinyl cyclic …

Photochemical Allylation of Alkanes Enabled by Nickel Catalysis

Y **, EWH Ng, T Fan, H Hirao, LZ Gong - ACS Catalysis, 2022 - ACS Publications
We have developed an allylic alkylation of alkanes by dual photo-HAT/nickel catalysis. In
this reaction, radical-type hydrogen-atom-transfer of the alkanes is enabled by …

Transformations of carbohydrate derivatives enabled by photocatalysis and visible light photochemistry

DJ Gorelik, SP Desai, S Jdanova, JA Turner… - Chemical …, 2024 - pubs.rsc.org
This review article highlights the diverse ways in which recent developments in the areas of
photocatalysis and visible light photochemistry are impacting synthetic carbohydrate …