Metal–organic network-forming glasses
The crystal–liquid–glass phase transition of coordination polymers (CPs) and metal–organic
frameworks (MOFs) offers attractive opportunities as a new class of amorphous materials …
frameworks (MOFs) offers attractive opportunities as a new class of amorphous materials …
Precise control over gas-transporting channels in zeolitic imidazolate framework glasses
O Smirnova, S Hwang, R Sajzew, L Ge, A Reupert… - Nature Materials, 2024 - nature.com
Porous metal–organic frameworks have emerged to resolve important challenges of our
modern society, such as CO2 sequestration. Zeolitic imidazolate frameworks (ZIFs) can …
modern society, such as CO2 sequestration. Zeolitic imidazolate frameworks (ZIFs) can …
Recent progress of amorphous and glassy coordination polymers
In recent decades, the amorphous state of crystalline coordination polymers (CPs)
constructed from metal ions and molecular bridging ligands via coordination bonds, has …
constructed from metal ions and molecular bridging ligands via coordination bonds, has …
Size-reduced low-crystallinity ZIF-62 for the preparation of mixed-matrix membranes for CH4/N2 separation
C Ma, Z Yang, X Guo, Z Qiao, C Zhong - Journal of Membrane Science, 2022 - Elsevier
CH 4/N 2 separation is of great significance for the utilization of unconventional natural gas,
however facing great difficulty due to the similarity of physical and chemical properties …
however facing great difficulty due to the similarity of physical and chemical properties …
Low‐temperature melting and glass formation of the zeolitic imidazolate frameworks ZIF‐62 and ZIF‐76 through ionic liquid incorporation
V Nozari, O Smirnova, JM Tuffnell… - Advanced Materials …, 2022 - Wiley Online Library
Hybrid glass formation offers a potential route for processing metal‐organic frameworks
(MOFs) in bulk shapes, however, only a small number of MOFs have proven to be meltable …
(MOFs) in bulk shapes, however, only a small number of MOFs have proven to be meltable …
Micro-optical elements from optical-quality ZIF-62 hybrid glasses by hot imprinting
O Smirnova, R Sajzew, SJ Finkelmeyer… - Nature …, 2024 - nature.com
Hybrid glasses derived from meltable metal-organic frameworks (MOFs) promise to combine
the intriguing properties of MOFs with the universal processing ability of glasses. However …
the intriguing properties of MOFs with the universal processing ability of glasses. However …
Amorphous MOFs for next generation supercapacitors and batteries
Metal–organic frameworks (MOFs) are porous materials comprised of metal nodes and
organic linkers, which feature highly tunable structures and compositions that can be …
organic linkers, which feature highly tunable structures and compositions that can be …
A review on the vitrification of metal coordination compounds and their photonic applications
MA Ali, X Liu, J Qiu - Journal of Non-Crystalline Solids, 2022 - Elsevier
The vitrification of metal coordination compounds (MCC) leads to the emerging of a new
family of glass with unique structures and properties. In this review, we discuss the recent …
family of glass with unique structures and properties. In this review, we discuss the recent …
Glassy behaviour of mechanically amorphised ZIF-62 isomorphs
Zeolitic imidazolate frameworks (ZIFs) can be melt-quenched to form glasses. Here, we
present an alternative route to glassy ZIFs via mechanically induced amorphisation. This …
present an alternative route to glassy ZIFs via mechanically induced amorphisation. This …
Supercooled Liquids in a Core–Shell Coordination Structure for Practical Long‐Term Energy Storage
X Zhang, Z Du, D He, Z Chen, Z Li, G Chen… - Advanced …, 2025 - Wiley Online Library
Mutual acquisition of phase‐stability and controllable phase‐transition becomes a
predominant criterion of phase‐change materials for the practical long‐term energy storage …
predominant criterion of phase‐change materials for the practical long‐term energy storage …