Photochemically triggered cheletropic formation of cyclopropenone (cC 3 H 2 O) from carbon monoxide and electronically excited acetylene

J Wang, NF Kleimeier, RN Johnson, S Gozem… - Physical Chemistry …, 2022 - pubs.rsc.org
For more than half a century, pericyclic reactions have played an important role in advancing
our fundamental understanding of cycloadditions, sigmatropic shifts, group transfer …

[HTML][HTML] Correlation balance for describing carbenes: An NOF study

L Franco, JFH Lew-Yee, JM del Campo - AIP Advances, 2023 - pubs.aip.org
Carbenes are a remarkable type of molecules because of the two electrons that might be
paired or unpaired, providing a singlet or a triplet state, respectively. The preference for one …

Competitive Reactivity of SO2 and NO2 with N-Heterocyclic Carbene: A Mechanistic Study

R Logdi, A Bag, AK Tiwari - The Journal of Physical Chemistry A, 2021 - ACS Publications
Recent DFT based molecular engineering to obtain stable oxathiirane S-oxide derivatives
evokes the recommencement of the use of carbenes for the sequestering of SO2, which has …

Computational search for metastable high-spin C5Hn (n= 4, 5, 6) species

MG Moreno-Armenta, HR Pearce, P Winter… - Computational and …, 2018 - Elsevier
A search for small hydrocarbon radicals with two electronic spin states of comparable
stability has identified 9 candidates among singlet and triplet states of various isomers of …

[CITATION][C] Towards the photophysical nature of the triphenylphosphine-stabilized nonagold cluster and its catalytic applications