Fe (II) redox chemistry in the environment

J Huang, A Jones, TD Waite, Y Chen, X Huang… - Chemical …, 2021 - ACS Publications
Iron (Fe) is the fourth most abundant element in the earth's crust and plays important roles in
both biological and chemical processes. The redox reactivity of various Fe (II) forms has …

Bacterial long-chain polyunsaturated fatty acids: their biosynthetic genes, functions, and practical use

K Yoshida, M Hashimoto, R Hori, T Adachi, H Okuyama… - Marine drugs, 2016 - mdpi.com
The nutritional and pharmaceutical values of long-chain polyunsaturated fatty acids (LC-
PUFAs) such as arachidonic, eicosapentaenoic and docosahexaenoic acids have been well …

Advanced oxidation process with peracetic acid and Fe (II) for contaminant degradation

J Kim, T Zhang, W Liu, P Du, JT Dobson… - … Science & Technology, 2019 - ACS Publications
Fe (II) is an excellent promoter for advanced oxidation processes (AOPs) because of its
environmental ubiquity and low toxicity. This study is among the first to characterize the …

Do we appropriately detect and understand singlet oxygen possibly generated in advanced oxidation processes by electron paramagnetic resonance spectroscopy?

Y Zong, L Chen, Y Zeng, J Xu, H Zhang… - Environmental …, 2023 - ACS Publications
Electron paramagnetic resonance (EPR) spectroscopy using sterically hindered amine is
extensively applied to detect singlet oxygen (1O2) possibly generated in advanced oxidation …

Production of abundant hydroxyl radicals from oxygenation of subsurface sediments

M Tong, S Yuan, S Ma, M **, D Liu… - … science & technology, 2016 - ACS Publications
Hydroxyl radicals (• OH) play a crucial role in the fate of redox-active substances in the
environment. Studies of the• OH production in nature has been constrained to surface …

Active iron phases regulate the abiotic transformation of organic carbon during redox fluctuation cycles of paddy soil

N Chen, Q Fu, T Wu, P Cui, G Fang, C Liu… - Environmental …, 2021 - ACS Publications
Iron (Fe) phases are tightly linked to the preservation rather than the loss of organic carbon
(OC) in soil; however, during redox fluctuations, OC may be lost due to Fe phase-mediated …

Active chlorine mediated ammonia oxidation revisited: Reaction mechanism, kinetic modelling and implications

C Zhang, D He, J Ma, TD Waite - Water research, 2018 - Elsevier
Ammonia nitrogen removal from wastewaters has gained much attention in recent decades
as a result of the environmental problems associated with discharge of excessive amounts …

Mechanistic insight into humic acid-enhanced hydroxyl radical production from Fe (II)-bearing clay mineral oxygenation

C Yu, Y Zhang, Y Lu, A Qian, P Zhang… - Environmental …, 2021 - ACS Publications
Hydroxyl radical (• OH) production by electron transfer from Fe (II)-bearing clay minerals to
oxygen has been increasingly reported. However, the influence of ubiquitous coexisting …

Effect of C/Fe Molar Ratio on H2O2 and OH Production during Oxygenation of Fe(II)-Humic Acid Coexisting Systems

Y Zhang, N Zhang, A Qian, C Yu… - … Science & Technology, 2022 - ACS Publications
Hydrogen peroxide (H2O2) and hydroxyl radical (• OH) production during oxygenation of
reduced iron (Fe (II)) and natural organic matter (NOM) in the subsurface has been …

Oxidizing impact induced by mackinawite (FeS) nanoparticles at oxic conditions due to production of hydroxyl radicals

D Cheng, S Yuan, P Liao, P Zhang - Environmental science & …, 2016 - ACS Publications
Mackinawite (FeS) nanoparticles have been extensively tested for reducing contaminants
under anoxic conditions, while the oxidizing impact induced by FeS under oxic conditions …