The mechanical bond in biological systems
The field of mechanically interlocked molecules (MIMs) has advanced rapidly in recent
years, with much work focused on their use in materials, sensing, and catalysis. However …
years, with much work focused on their use in materials, sensing, and catalysis. However …
Single-molecule studies on artificial small-molecule machines
ZH Zhang, HN Feng, G Chi, DA Leigh… - CCS Chemistry, 2023 - chinesechemsoc.org
Molecular machines transduce energy from one form to another through controlled motion in
response to stimuli. Despite the ubiquitous use of molecular machines in biology …
response to stimuli. Despite the ubiquitous use of molecular machines in biology …
Advancements and strategic approaches in catenane synthesis
Q Chen, K Zhu - Chemical Society Reviews, 2024 - pubs.rsc.org
Catenanes, a distinctive category of mechanically interlocked molecules composed of
intertwined macrocycles, have undergone significant advancements since their initial stages …
intertwined macrocycles, have undergone significant advancements since their initial stages …
Self-sorting as a versatile strategy in the synthesis of rotaxanes and catenanes
Rotaxanes, pseudorotaxanes, and catenanes have attracted the interest of many
researchers because of the special features provided by the mechanical bond. The selective …
researchers because of the special features provided by the mechanical bond. The selective …
Controllable Aggregation-Induced Emission and Förster Resonance Energy Transfer Behaviors of Bistable [c2] Daisy Chain Rotaxanes for White-Light Emission …
Bistable [c 2] daisy chain rotaxanes with respective extended and contracted forms of [c 2] A
and [c 2] B containing a blue-emissive anthracene (AN) donor and orange-emissive …
and [c 2] B containing a blue-emissive anthracene (AN) donor and orange-emissive …
The Future of Bioinspired Innovation: Exploring the Potential of Nanobiomimetics
Leonardo da Vinci's 15th-century design of flying machines, inspired by the anatomy and
flight of birds, stands as classic example of organismal biomimetics. His sketches of …
flight of birds, stands as classic example of organismal biomimetics. His sketches of …
Self-Resetting Bistable Redox Molecular Machines for Fullerene Recognition
Addressing control over molecular machines resulting in variable output modulation by
mimicking nature mechanisms is a current hot topic. The exploitation of reversibility in …
mimicking nature mechanisms is a current hot topic. The exploitation of reversibility in …
Anion-templated synthesis of a switchable fluorescent [2] catenane with sulfate sensing capability
Anion templation strategies have facilitated the synthesis of various catenane and rotaxane
hosts capable of strong and selective binding of anions in competitive solvents. However …
hosts capable of strong and selective binding of anions in competitive solvents. However …
Main group molecular switches with swivel bifurcated to trifurcated hydrogen bond mode of action
G Hum, SJI Phang, HC Ong, F León… - Journal of the …, 2023 - ACS Publications
Artificial molecular machines have captured the full attention of the scientific community
since Jean-Pierre Sauvage, Fraser Stoddart, and Ben Feringa were awarded the 2016 …
since Jean-Pierre Sauvage, Fraser Stoddart, and Ben Feringa were awarded the 2016 …
Modulating the shuttling motion of [2] rotaxanes built of p-xylylenediamine units through permethylation at the benzylic positions of the ring
In this study, we show the effect of the gem-dimethyl substitution at the four benzylic carbons
of the ring on the internal dynamics of two-station [2] rotaxanes. Such structural modification …
of the ring on the internal dynamics of two-station [2] rotaxanes. Such structural modification …