Since the last five decades, polymer-derived ceramics (PDCs) are in use and envisaged for
a variety of applications. The transition of a precursor to an inorganic ceramic by pyrolysis …

The elaboration of solids from the molecular scale by a kinetically controlled methodology is
one of the main challenges of molecular chemistry. In the long term, this should permit the …

Silicon carbide ceramic fibers derived from organometallic polymer precursors offer
exceptional opportunities for the development of high-temperature ceramic and metal matrix …

Polycarbosilanes are unique precursors in the preparation of silicon carbide ceramics and
silicon carbide fibers. The conventional production is carried out upon harsh reaction …

Tailoring of polysilanes with given architectures and reactivities is a great challenge in the
field of SiC pre‐ceramic polymers. This paper reviews recent polysilane and related …

Recent years have witnessed great progress in the application of calcium-based catalysts in
a variety of organic transformations, including hydrofuctionalization, dehydrogenative …

Polycarbosilanes with SiH2 units in the main chain may undergo diverse reactions to access
a family of functionalized polymers with enhanced added values. However, the preparation …

A liquid carbon-rich SiAlCN precursor is facilely synthetized by hydrosilylation between
liquid polyaluminocarbosilane (LPACS) and 1, 3, 5, 7-tetravinyl-1, 3, 5, 7 …

Dihydridocarbonyltris (triphenylphosphine) ruthenium, activated with a stoichiometric
amount of styrene, catalyzes the hydrosilylation polymerization of dimethylsilyloxyaryl …

Y= Z=; III, X= Z= vinyl, Y=; IV, X= Z= vinyl, Y= vinyl and H) have been prepared by means of
hydrosilylation polymerization, followed bychemical transformation of the resulting polymer …