Probing zeolites by vibrational spectroscopies

S Bordiga, C Lamberti, F Bonino, A Travert… - Chemical Society …, 2015 - pubs.rsc.org
This review addresses the most relevant aspects of vibrational spectroscopies (IR, Raman
and INS) applied to zeolites and zeotype materials. Surface Brønsted and Lewis acidity and …

Two-dimensional zeolite materials: structural and acidity properties

E Schulman, W Wu, D Liu - Materials, 2020 - mdpi.com
Zeolites are generally defined as three-dimensional (3D) crystalline microporous
aluminosilicates in which silicon (Si4+) and aluminum (Al3+) are coordinated tetrahedrally …

Identification and characterization of surface hydroxyl groups by infrared spectroscopy

K Hadjiivanov - Advances in Catalysis, 2014 - Elsevier
Surface hydroxyl groups are active centers in many catalytic reactions and can play an
important role during catalyst preparation. In this chapter, the application of infrared …

MWW and MFI frameworks as model layered zeolites: structures, transformations, properties, and activity

M Shamzhy, B Gil, M Opanasenko, WJ Roth… - Acs Catalysis, 2021 - ACS Publications
Porous solids containing internal pores with sizes ranging from angstroms to nanometers
are highly useful and valuable in the catalysis, separation, and storage of molecules …

Organic matter and mineral composition of silicate soils: FTIR comparison study by photoacoustic, diffuse reflectance, and attenuated total reflection modalities

DS Volkov, OB Rogova, MA Proskurnin - Agronomy, 2021 - mdpi.com
This study aims to compare photoacoustic (FTIR–PAS), diffuse reflectance (DRIFT), and
attenuated total reflection (ATR) FTIR modalities in the wide wavenumber range from NIR …

Catalytic combustion of VOC on sandwich-structured Pt@ ZSM-5 nanosheets prepared by controllable intercalation

G Liu, Y Tian, B Zhang, L Wang, X Zhang - Journal of hazardous materials, 2019 - Elsevier
A sandwich-structured Pt@ ZSM-5 nanosheets (Pt@ PZN-2) was fabricated by controllable
intercalating Pt nanoparticles between ZSM-5 single-layer sheets via electrostatic …

Process optimization of biodiesel production via esterification of oleic acid using sulfonated hierarchical mesoporous ZSM-5 as an efficient heterogeneous catalyst

NM Marzouk, AOA El Naga, SA Younis… - Journal of …, 2021 - Elsevier
The development of effective heterogeneous catalysts for the production of biodiesel from
low-cost feedstocks containing large amounts of free fatty acids has lately become one of the …

Spectroscopic expression of the external surface sites of H-ZSM-5

L Treps, C Demaret, D Wisser… - The Journal of …, 2021 - ACS Publications
The nature and spectroscopic expression of external surface sites of zeolites, in particular
ZSM-5, is a long-debated question. Herein, we use three cutting-edge techniques: Fourier …

Ethene oligomerization on nickel microporous and mesoporous-supported catalysts: Investigation of the active sites

R Henry, M Komurcu, Y Ganjkhanlou, RY Brogaard… - Catalysis Today, 2018 - Elsevier
Nickel-containing mesoporous (using Al 2 O 3 or SiO 2-Al 2 O 3 support) and microporous
(using nano-or micro-crystalline Beta zeolite support) catalysts were prepared by ion …

Disentangling Brønsted acid sites and hydrogen-bonded silanol groups in high-silica zeolite H-ZSM-5

C Schroeder, V Siozios, M Hunger… - The Journal of …, 2020 - ACS Publications
Hydrogen-bonded SiOH defects and Brønsted acidic bridging OH groups, defined as
Brønsted acid sites (BAS), yield overlap** signals in 1H MAS NMR and FTIR …