Active transition–metal complexes based on relatively inexpensive metals are considered to
be a desirable method for sustainable human industrial growth. Considering their cost …

Pincer complexes have represented a group of very important species in organometallic
chemistry in the last decade. Among these, phosphinite POCOP pincer complexes have …

The new chiral ligands (R)-/(S)-N-((1-phenylethyl) carbamothioyl) benzamide (L1/L2),(R)-
/(S)-N-((1-phenylethyl) carbamothioyl) thiophene-2-carboxamide (L3/L4), and (R)-/(S)-N-((1 …

A survey of the electronic and steric characteristics of anionic (R PCP, R POCOP, R PNCNP)
and neutral (R PNP, R PONOP, R PNNNP) phosphine terdentate ligands is presented. A …

A description of the vertiginous development of the chemistry of POCOP–Ni complexes and
their applications is described. Recent advances include the discovery and initially …

The hydrogenation processes, and all the reactions that formally add two hydrogen atoms to
an unsaturated bond, are among the most used transformations in the manufacture of bulk …

A novel cationic dinuclear ruthenium complex [RuCl (HL)(TFTPP)] 2 (H2L= 2, 6-bis (5-
phenyl-1H-pyrazol-3-yl) pyridine; TFTPP= tri (p-trifluoromethylphenyl) phosphine) has been …

The synthesis of perfluoroalkyl-substituted “pincer”-type PCP ligands, 1, 3-C6H4 (CH2P (Rf)
2) 2 (Rf= CF3, C2F5), and platinum coordination studies (Rf= CF3) are reported. 1, 3-C6H4 …

A novel Schiff base N3, N3′-di-2-hydroxybenzylidene-[2, 2′] bipyridinyl-3, 3′-diamine, 1
was synthesized from condensation of salicylaldehyde with 3, 3′-diamino-2, 2′-bipyridine …

A variety of phosphinite based on ferrocenyl moiety possessing central chirality have been
screened as ligands for ruthenium (II)-catalyzed transfer hydrogenation of acetophenone …