Hydrophilic ligands and their application in aqueous-phase metal-catalyzed reactions
KH Shaughnessy - Chemical reviews, 2009 - ACS Publications
Water is truly ubiquitous. Approximately 80% of the earth's surface is covered by water,
although only 1% of this is drinkable water. Water is the solvent of life and makes up about …
although only 1% of this is drinkable water. Water is the solvent of life and makes up about …
N-heterocyclic carbene transition metal complexes for catalysis in aqueous media
The last decade has seen an increasing number of reports on the use of NHC–metal
complexes for catalysis in water, therefore this review is aimed to introduce the whole …
complexes for catalysis in water, therefore this review is aimed to introduce the whole …
Rhodium and iridium complexes of N-heterocyclic carbenes via transmetalation: Structure and dynamics
AR Chianese, X Li, MC Janzen, JW Faller… - …, 2003 - ACS Publications
Rhodium and iridium complexes of N-heterocyclic carbenes (3a− c and 4a− c) were
obtained by transmetalation from the corresponding Ag (I) complexes. The structure of 3b …
obtained by transmetalation from the corresponding Ag (I) complexes. The structure of 3b …
Synthesis and application of water‐soluble NHC transition‐metal complexes
LA Schaper, SJ Hock, WA Herrmann… - Angewandte Chemie …, 2013 - Wiley Online Library
We provide an overview on the state‐of‐the‐art in transition‐metal complexes formed with
water‐soluble NHC ligands. Paths to introducing water solubility by ligand design are …
water‐soluble NHC ligands. Paths to introducing water solubility by ligand design are …
Water in N-heterocyclic carbene-assisted catalysis
Water is one of the most abundant molecules on earth. It is inexpensive, especially when
compared to organic solvents, nonflammable, and nontoxic, it has a large heat capacity, and …
compared to organic solvents, nonflammable, and nontoxic, it has a large heat capacity, and …
Glycerol and derived solvents: new sustainable reaction media for organic synthesis
AE Díaz-Álvarez, J Francos, B Lastra-Barreira… - Chemical …, 2011 - pubs.rsc.org
The rapid growth of the biodiesel industry has led to a large surplus of its major byproduct, ie
glycerol, for which new applications need to be found. Research efforts in this area have …
glycerol, for which new applications need to be found. Research efforts in this area have …
Stabilization of Organometallic Species Achieved by the Use of N‐Heterocyclic Carbene (NHC) Ligands
NM Scott, SP Nolan - European journal of inorganic chemistry, 2005 - Wiley Online Library
This review describes the stabilization of various coordinatively unsaturated metal centers
through the incorporation of N‐heterocyclic carbene (NHC) ligands. Such species are more …
through the incorporation of N‐heterocyclic carbene (NHC) ligands. Such species are more …
Palladium-catalyzed cross-coupling in aqueous media: recent progress and current applications
KH Shaughnessy, RB DeVasher - Current Organic Chemistry, 2005 - ingentaconnect.com
Water has attracted significant attention as an alternative solvent for homogeneous metal-
catalyzed reactions because it is a non-toxic, nonflammable solvent that can allow for …
catalyzed reactions because it is a non-toxic, nonflammable solvent that can allow for …
Novel sulfonated N-heterocyclic carbene gold (I) complexes: Homogeneous gold catalysis for the hydration of terminal alkynes in aqueous media
A Almássy, CE Nagy, AC Bényei, F Joó - Organometallics, 2010 - ACS Publications
A series of novel water-soluble AuI complexes using sulfonated N-heterocyclic
imidazolylidene carbenes as ligands was prepared by transmetalation from the …
imidazolylidene carbenes as ligands was prepared by transmetalation from the …
Facile Synthesis of [(NHC) MX (Cod)] and [(NHC) MCl (CO) 2](M= Rh, Ir; X= Cl, I) Complexes
R Savka, H Plenio - Dalton Transactions, 2015 - pubs.rsc.org
Facile synthesis of [(NHC)MX(cod)] and [(NHC)MCl(CO) 2 ] (M = Rh, Ir; X = Cl, I) complexes -
Dalton Transactions (RSC Publishing) DOI:10.1039/C4DT03449J Royal Society of Chemistry …
Dalton Transactions (RSC Publishing) DOI:10.1039/C4DT03449J Royal Society of Chemistry …