Toolbox for distal C–H bond functionalizations in organic molecules

SK Sinha, S Guin, S Maiti, JP Biswas, S Porey… - Chemical …, 2021 - ACS Publications
Transition-metal-catalyzed C–H activation has developed a contemporary approach to the
omnipresent area of retrosynthetic disconnection. Scientific researchers have been tempted …

3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

Ultrahigh peroxymonosulfate utilization efficiency over CuO nanosheets via heterogeneous Cu (III) formation and preferential electron transfer during degradation of …

Y Wei, J Miao, J Ge, J Lang, C Yu… - Environmental …, 2022 - ACS Publications
In persulfate activation by copper-based catalysts, high-valent copper (Cu (III)) is an
overlooked reactive intermediate that contributes to efficient persulfate utilization and …

Efficient electrocatalytic valorization of chlorinated organic water pollutant to ethylene

C Choi, X Wang, S Kwon, JL Hart, CL Rooney… - Nature …, 2023 - nature.com
Electrochemistry can provide an efficient and sustainable way to treat environmental waters
polluted by chlorinated organic compounds. However, the electrochemical valorization of 1 …

Transition metal–catalyzed remote C─ H borylation: An emerging synthetic tool

MMM Hassan, S Guria, S Dey, J Das… - Science …, 2023 - science.org
Transition metal–catalyzed C─ H bond activation and borylation is a powerful synthetic
method that offers versatile synthetic transformation from organoboron compounds to …

From C4 to C7: innovative strategies for site-selective functionalization of indole C–H bonds

J Wen, Z Shi - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus The widespread presence of hydrocarbons makes C–H functionalization an
attractive alternative to traditional cross-coupling methods. As indole is an important …

Arene diversification through distal C(sp2)−H functionalization

U Dutta, S Maiti, T Bhattacharya, D Maiti - Science, 2021 - science.org
BACKGROUND Organic synthetic chemistry has facilitated the production of medicines,
agrochemicals, food, polymers, dyes, and more through step-and atom-economical …

Recent applications of C–H functionalization in complex natural product synthesis

DJ Abrams, PA Provencher, EJ Sorensen - Chemical Society Reviews, 2018 - pubs.rsc.org
In this review, recent examples featuring C–H functionalization in the synthesis of complex
natural products are discussed. A focus is given to the way in which C–H functionalization …

Installing the “magic methyl”–C–H methylation in synthesis

D Aynetdinova, MC Callens, HB Hicks… - Chemical Society …, 2021 - pubs.rsc.org
The selective and efficient C–H methylation of sp2 and sp3 carbon centres has become a
powerful transformation in the synthetic toolbox. Due to the potential for profound changes to …

Weak-coordination in C–H bond functionalizations catalyzed by 3d metals

R Mandal, B Garai, B Sundararaju - ACS Catalysis, 2022 - ACS Publications
Transition-metal-catalyzed C–H bond functionalizations have had an enormous influence on
organic synthesis in recent times. However, the use of low-abundance 4d and 5d metals is …