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Toolbox for distal C–H bond functionalizations in organic molecules
Transition-metal-catalyzed C–H activation has developed a contemporary approach to the
omnipresent area of retrosynthetic disconnection. Scientific researchers have been tempted …
omnipresent area of retrosynthetic disconnection. Scientific researchers have been tempted …
3d transition metals for C–H activation
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …
notable applications to material sciences, crop protection, drug discovery, and …
Ultrahigh peroxymonosulfate utilization efficiency over CuO nanosheets via heterogeneous Cu (III) formation and preferential electron transfer during degradation of …
In persulfate activation by copper-based catalysts, high-valent copper (Cu (III)) is an
overlooked reactive intermediate that contributes to efficient persulfate utilization and …
overlooked reactive intermediate that contributes to efficient persulfate utilization and …
Efficient electrocatalytic valorization of chlorinated organic water pollutant to ethylene
Electrochemistry can provide an efficient and sustainable way to treat environmental waters
polluted by chlorinated organic compounds. However, the electrochemical valorization of 1 …
polluted by chlorinated organic compounds. However, the electrochemical valorization of 1 …
Transition metal–catalyzed remote C─ H borylation: An emerging synthetic tool
Transition metal–catalyzed C─ H bond activation and borylation is a powerful synthetic
method that offers versatile synthetic transformation from organoboron compounds to …
method that offers versatile synthetic transformation from organoboron compounds to …
From C4 to C7: innovative strategies for site-selective functionalization of indole C–H bonds
J Wen, Z Shi - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus The widespread presence of hydrocarbons makes C–H functionalization an
attractive alternative to traditional cross-coupling methods. As indole is an important …
attractive alternative to traditional cross-coupling methods. As indole is an important …
Arene diversification through distal C(sp2)−H functionalization
BACKGROUND Organic synthetic chemistry has facilitated the production of medicines,
agrochemicals, food, polymers, dyes, and more through step-and atom-economical …
agrochemicals, food, polymers, dyes, and more through step-and atom-economical …
Recent applications of C–H functionalization in complex natural product synthesis
DJ Abrams, PA Provencher, EJ Sorensen - Chemical Society Reviews, 2018 - pubs.rsc.org
In this review, recent examples featuring C–H functionalization in the synthesis of complex
natural products are discussed. A focus is given to the way in which C–H functionalization …
natural products are discussed. A focus is given to the way in which C–H functionalization …
Installing the “magic methyl”–C–H methylation in synthesis
D Aynetdinova, MC Callens, HB Hicks… - Chemical Society …, 2021 - pubs.rsc.org
The selective and efficient C–H methylation of sp2 and sp3 carbon centres has become a
powerful transformation in the synthetic toolbox. Due to the potential for profound changes to …
powerful transformation in the synthetic toolbox. Due to the potential for profound changes to …
Weak-coordination in C–H bond functionalizations catalyzed by 3d metals
Transition-metal-catalyzed C–H bond functionalizations have had an enormous influence on
organic synthesis in recent times. However, the use of low-abundance 4d and 5d metals is …
organic synthesis in recent times. However, the use of low-abundance 4d and 5d metals is …