Bioinspired framework catalysts: From enzyme immobilization to biomimetic catalysis

KY Wang, J Zhang, YC Hsu, H Lin, Z Han… - Chemical …, 2023‏ - ACS Publications
Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency
and selectivity. However, the structural complexity and vulnerability hamper the application …

Confining enzymes in porous organic frameworks: from synthetic strategy and characterization to healthcare applications

S Huang, G Chen, G Ouyang - Chemical Society Reviews, 2022‏ - pubs.rsc.org
Enzymes are a class of natural catalysts with high efficiency, specificity, and selectivity
unmatched by their synthetic counterparts and dictate a myriad of reactions that constitute …

Reticular chemistry for highly porous metal–organic frameworks: The chemistry and applications

Z Chen, KO Kirlikovali, P Li… - Accounts of chemical …, 2022‏ - ACS Publications
Conspectus Current global crises related to clean energy and the environment entail the
development of materials that are capable of addressing these challenges. Metal–organic …

MOF-enabled confinement and related effects for chemical catalyst presentation and utilization

J Liu, TA Goetjen, Q Wang, JG Knapp… - Chemical Society …, 2022‏ - pubs.rsc.org
A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …

Metal–organic framework-based enzyme biocomposites

W Liang, P Wied, F Carraro, CJ Sumby… - Chemical …, 2021‏ - ACS Publications
Because of their efficiency, selectivity, and environmental sustainability, there are significant
opportunities for enzymes in chemical synthesis and biotechnology. However, as the three …

A historical overview of the activation and porosity of metal–organic frameworks

X Zhang, Z Chen, X Liu, SL Hanna, X Wang… - Chemical Society …, 2020‏ - pubs.rsc.org
Since the first reports of metal–organic frameworks (MOFs), this unique class of crystalline,
porous materials has garnered increasing attention in a wide variety of applications such as …

Metal–organic frameworks meet polymers: from synthesis strategies to healthcare applications

AK Bindra, D Wang, Y Zhao - Advanced Materials, 2023‏ - Wiley Online Library
Metal–organic frameworks (MOFs) have been at the forefront of nanotechnological research
for the past decade owing to their high porosity, high surface area, diverse configurations …

State of the art and prospects in metal–organic framework (MOF)-based and MOF-derived nanocatalysis

Q Wang, D Astruc - Chemical reviews, 2019‏ - ACS Publications
Metal–organic framework (MOF) nanoparticles, also called porous coordination polymers,
are a major part of nanomaterials science, and their role in catalysis is becoming central …

Hierarchically micro-, meso-, and macro-porous MOF nanosystems for localized cross-scale dual-biomolecule loading and guest-carrier cooperative anticancer …

Q Ke, K Jiang, H Li, L Zhang, B Chen - ACS nano, 2024‏ - ACS Publications
Mass transfer of bulky molecules, eg., bioenzymes, particularly for cross-scale
multibiomolecules, imposes serious challenges for microporous metal–organic frameworks …

Green and scalable fabrication of high‐performance biocatalysts using covalent organic frameworks as enzyme carriers

Y Zheng, S Zhang, J Guo, R Shi, J Yu… - Angewandte Chemie …, 2022‏ - Wiley Online Library
Enzyme immobilization is essential to the commercial viability of various critical large‐scale
biocatalytic processes. However, challenges remain for the immobilization systems, such as …