Design and applications of water-soluble coordination cages

EG Percástegui, TK Ronson, JR Nitschke - Chemical Reviews, 2020 - ACS Publications
Compartmentalization of the aqueous space within a cell is necessary for life. In similar
fashion to the nanometer-scale compartments in living systems, synthetic water-soluble …

Metal–organic cages for molecular separations

D Zhang, TK Ronson, YQ Zou, JR Nitschke - Nature Reviews Chemistry, 2021 - nature.com
Separation technology is central to industries as diverse as petroleum, pharmaceuticals,
mining and life sciences. Metal–organic cages, a class of molecular containers formed via …

Chemical reactivity under nanoconfinement

AB Grommet, M Feller, R Klajn - Nature nanotechnology, 2020 - nature.com
Confining molecules can fundamentally change their chemical and physical properties.
Confinement effects are considered instrumental at various stages of the origins of life, and …

Metallosupramolecular cages: from design principles and characterisation techniques to applications

AJ McConnell - Chemical Society Reviews, 2022 - pubs.rsc.org
Although metallosupramolecular cages are self-assembled from seemingly simple building
blocks, metal ions and organic ligands, architectures of increasingly large size and …

Heterometallic cages: synthesis and applications

LK Moree, LAV Faulkner, JD Crowley - Chemical Society Reviews, 2024 - pubs.rsc.org
High symmetry metallosupramolecular architectures (MSAs) have been exploited for a
range of applications including molecular recognition, catalysis and drug delivery. Recently …

Water-soluble self-assembled cage with triangular metal–metal-bonded units enabling the sequential selective separation of alkanes and isomeric molecules

LJ Wang, S Bai, YF Han - Journal of the American Chemical …, 2022 - ACS Publications
The selective separation of structurally similar aliphatic/aromatic hydrocarbons is an
essential goal in industrial processes. In this study, we report the synthesis of a water …

Bent anthracene dimers as versatile building blocks for supramolecular capsules

M Yoshizawa, L Catti - Accounts of chemical research, 2019 - ACS Publications
Conspectus This Account provides a comprehensive summary of our 1-decade-long
investigations into bent anthracene dimers as versatile building blocks for supramolecular …

Stabilization of reactive species by supramolecular encapsulation

A Galan, P Ballester - Chemical Society Reviews, 2016 - pubs.rsc.org
Molecular containers have attracted the interest of supramolecular chemists since the early
beginnings of the field. Cavitands' inner cavities were quickly exploited by Cram and …

Enantiopure trigonal bipyramidal coordination cages templated by in situ self-organized D2h-symmetric anions

S Guo, WW Zhan, FL Yang, J Zhou, YH Duan… - Nature …, 2024 - nature.com
The control of a molecule's geometry, chirality, and physical properties has long been a
challenging pursuit. Our study introduces a dependable method for assembling D 3 …

Reversible chromism of spiropyran in the cavity of a flexible coordination cage

D Samanta, D Galaktionova, J Gemen… - Nature …, 2018 - nature.com
Confining molecules to volumes only slightly larger than the molecules themselves can
profoundly alter their properties. Molecular switches—entities that can be toggled between …