Design and applications of water-soluble coordination cages
Compartmentalization of the aqueous space within a cell is necessary for life. In similar
fashion to the nanometer-scale compartments in living systems, synthetic water-soluble …
fashion to the nanometer-scale compartments in living systems, synthetic water-soluble …
Metal–organic cages for molecular separations
Separation technology is central to industries as diverse as petroleum, pharmaceuticals,
mining and life sciences. Metal–organic cages, a class of molecular containers formed via …
mining and life sciences. Metal–organic cages, a class of molecular containers formed via …
Chemical reactivity under nanoconfinement
Confining molecules can fundamentally change their chemical and physical properties.
Confinement effects are considered instrumental at various stages of the origins of life, and …
Confinement effects are considered instrumental at various stages of the origins of life, and …
Metallosupramolecular cages: from design principles and characterisation techniques to applications
AJ McConnell - Chemical Society Reviews, 2022 - pubs.rsc.org
Although metallosupramolecular cages are self-assembled from seemingly simple building
blocks, metal ions and organic ligands, architectures of increasingly large size and …
blocks, metal ions and organic ligands, architectures of increasingly large size and …
Heterometallic cages: synthesis and applications
High symmetry metallosupramolecular architectures (MSAs) have been exploited for a
range of applications including molecular recognition, catalysis and drug delivery. Recently …
range of applications including molecular recognition, catalysis and drug delivery. Recently …
Water-soluble self-assembled cage with triangular metal–metal-bonded units enabling the sequential selective separation of alkanes and isomeric molecules
LJ Wang, S Bai, YF Han - Journal of the American Chemical …, 2022 - ACS Publications
The selective separation of structurally similar aliphatic/aromatic hydrocarbons is an
essential goal in industrial processes. In this study, we report the synthesis of a water …
essential goal in industrial processes. In this study, we report the synthesis of a water …
Bent anthracene dimers as versatile building blocks for supramolecular capsules
Conspectus This Account provides a comprehensive summary of our 1-decade-long
investigations into bent anthracene dimers as versatile building blocks for supramolecular …
investigations into bent anthracene dimers as versatile building blocks for supramolecular …
Stabilization of reactive species by supramolecular encapsulation
Molecular containers have attracted the interest of supramolecular chemists since the early
beginnings of the field. Cavitands' inner cavities were quickly exploited by Cram and …
beginnings of the field. Cavitands' inner cavities were quickly exploited by Cram and …
Enantiopure trigonal bipyramidal coordination cages templated by in situ self-organized D2h-symmetric anions
S Guo, WW Zhan, FL Yang, J Zhou, YH Duan… - Nature …, 2024 - nature.com
The control of a molecule's geometry, chirality, and physical properties has long been a
challenging pursuit. Our study introduces a dependable method for assembling D 3 …
challenging pursuit. Our study introduces a dependable method for assembling D 3 …
Reversible chromism of spiropyran in the cavity of a flexible coordination cage
Confining molecules to volumes only slightly larger than the molecules themselves can
profoundly alter their properties. Molecular switches—entities that can be toggled between …
profoundly alter their properties. Molecular switches—entities that can be toggled between …