Catalytic systems for the cross‐linking of organosilicon polymers

D Wang, J Klein, E Mejía - Chemistry–An Asian Journal, 2017 - Wiley Online Library
Silicones and silicone rubbers are omnipresent in household and industrial products such
as lubricants, coatings, sealants, insulators, medical devices, etc. This plethora of …

[PDF][PDF] Review of organotin compounds: chemistry and applications

D Ghazi, Z Rasheed, E Yousif - development, 2018 - academia.edu
Organotin compounds find a bigger range of technological and industrial applications than
the organic compounds of any other metal. Many of these applications involve catalysis or …

New control over silicone synthesis using SiH chemistry: The Piers–Rubinsztajn reaction

MA Brook - Chemistry–A European Journal, 2018 - Wiley Online Library
There is a strong imperative to synthesize polymers with highly controlled structures and
narrow property ranges. Silicone polymers do not lend themselves to this paradigm because …

Digital light processing 3D printing of PDMS-based soft and elastic materials with tunable mechanical properties

K Du, J Basuki, V Glattauer, C Mesnard… - ACS Applied Polymer …, 2021 - ACS Publications
Herein, a family of thiourea containing silicone-based photoresins suitable for creating
silicone objects with excellent elasticity was developed for use in conventional digital light …

Thermoplastic silicone elastomers through self-association of pendant coumarin groups

AS Fawcett, MA Brook - Macromolecules, 2014 - ACS Publications
Although there are many benefits associated with thermoplastic elastomeric silicones, very
few examples exist: silicone elastomers are normally thermoset materials. We have …

Bioinspired high-performance silicone elastomers by catalyst-free dopamine cross-linking

Z Liu, D Hu, C Zheng, K Yu, X Zhang… - Industrial & Engineering …, 2024 - ACS Publications
Silicone elastomers, as good sealants and adhesives, have been widely applied in
protective coatings, architectural decoration, electronic packaging, and other fields …

Metal-Free Reduction of Secondary and Tertiary N-Phenyl Amides by Tris(pentafluorophenyl)boron-Catalyzed Hydrosilylation

RC Chadwick, V Kardelis, P Lim… - The Journal of Organic …, 2014 - ACS Publications
Tris (pentafluorophenyl) boron B (C6F5) 3 is an effective catalyst for the hydrosilylative
reduction of tertiary and N-phenyl secondary amides. It allows for the mild reduction of a …

Utilization of softwood lignin as both crosslinker and reinforcing agent in silicone elastomers

J Zhang, Y Chen, P Sewell, MA Brook - Green Chemistry, 2015 - pubs.rsc.org
Lignin, the second most abundant naturally occurring organic polymer on earth, is normally
used only as a source of fuel because of the difficulties in processing it for other applications …

[HTML][HTML] Tris (pentafluorophenyl) borane-catalyzed Hydride transfer reactions in Polysiloxane Chemistry—Piers–Rubinsztajn reaction and related processes

S Rubinsztajn, J Chojnowski, U Mizerska - Molecules, 2023 - mdpi.com
Tris (pentafluorophenyl) borane (TPFPB) is a unique Lewis acid that catalyzes the
condensation between hydrosilanes (Si-H) and alkoxysilanes (Si-OR), leading to the …

Printing silicone-based hydrophobic barriers on paper for microfluidic assays using low-cost ink jet printers

V Rajendra, C Sicard, JD Brennan, MA Brook - Analyst, 2014 - pubs.rsc.org
Paper-based microfluidic devices exhibit many advantages for biological assays. Normally,
the assays are restricted to certain areas of the paper by hydrophobic barriers comprised of …