The chemistry and applications of hafnium and cerium (IV) metal–organic frameworks

Z Hu, Y Wang, D Zhao - Chemical Society Reviews, 2021 - pubs.rsc.org
The coordination connection of organic linkers to the metal clusters leads to the formation of
metal–organic frameworks (MOFs), where the metal clusters and ligands are spatially …

Electronic structure modeling of metal–organic frameworks

JL Mancuso, AM Mroz, KN Le, CH Hendon - Chemical reviews, 2020 - ACS Publications
Owing to their molecular building blocks, yet highly crystalline nature, metal–organic
frameworks (MOFs) sit at the interface between molecule and material. Their diverse …

[HTML][HTML] Understanding the diversity of the metal-organic framework ecosystem

SM Moosavi, A Nandy, KM Jablonka, D Ongari… - Nature …, 2020 - nature.com
Millions of distinct metal-organic frameworks (MOFs) can be made by combining metal
nodes and organic linkers. At present, over 90,000 MOFs have been synthesized and over …

An artificial sodium-selective subnanochannel

J Lu, G Jiang, H Zhang, B Qian, H Zhu, Q Gu, Y Yan… - Science …, 2023 - science.org
Single-ion selectivity with high precision has long been pursued for fundamental bioinspired
engineering and applications such as in ion separation and energy conversion. However, it …

Performance-based screening of porous materials for carbon capture

AH Farmahini, S Krishnamurthy, D Friedrich… - Chemical …, 2021 - ACS Publications
Computational screening methods have changed the way new materials and processes are
discovered and designed. For adsorption-based gas separations and carbon capture, recent …

[PDF][PDF] An all-round AI-Chemist with a scientific mind

Q Zhu, F Zhang, Y Huang, H **ao… - National Science …, 2022 - academic.oup.com
The realization of automated chemical experiments by robots unveiled the prelude to an
artificial intelligence (AI) laboratory. Several AI-based systems or robots with specific …

Construction of angstrom-scale ion channels with versatile pore configurations and sizes by metal-organic frameworks

X Li, G Jiang, M Jian, C Zhao, J Hou… - Nature …, 2023 - nature.com
Controllable fabrication of angstrom-size channels has been long desired to mimic
biological ion channels for the fundamental study of ion transport. Here we report a strategy …

A data-science approach to predict the heat capacity of nanoporous materials

SM Moosavi, BÁ Novotny, D Ongari, E Moubarak… - Nature materials, 2022 - nature.com
The heat capacity of a material is a fundamental property of great practical importance. For
example, in a carbon capture process, the heat required to regenerate a solid sorbent is …

[HTML][HTML] Recent advances, opportunities, and challenges in high-throughput computational screening of MOFs for gas separations

H Daglar, S Keskin - Coordination Chemistry Reviews, 2020 - Elsevier
In the last two decades, metal organic frameworks (MOFs) have gained significant attention
as adsorbent and membrane materials for gas separations. Due to the large number and …

The chemistry of reticular framework nanoparticles: MOF, ZIF, and COF materials

E Ploetz, H Engelke, U Lächelt… - Advanced Functional …, 2020 - Wiley Online Library
Nanoparticles have become a vital part of a vast number of established processes and
products; they are used as catalysts, in cosmetics, and even by the pharmaceutical industry …