Metallaphotoredox: the merger of photoredox and transition metal catalysis
The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …
Technological innovations in photochemistry for organic synthesis: flow chemistry, high-throughput experimentation, scale-up, and photoelectrochemistry
Photoinduced chemical transformations have received in recent years a tremendous amount
of attention, providing a plethora of opportunities to synthetic organic chemists. However …
of attention, providing a plethora of opportunities to synthetic organic chemists. However …
Photons or electrons? A critical comparison of electrochemistry and photoredox catalysis for organic synthesis
Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …
Photochemical and electrochemical applications of proton-coupled electron transfer in organic synthesis
We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …
The hitchhiker's guide to flow chemistry∥
Flow chemistry involves the use of channels or tubing to conduct a reaction in a continuous
stream rather than in a flask. Flow equipment provides chemists with unique control over …
stream rather than in a flask. Flow equipment provides chemists with unique control over …
Photocatalysis in the life science industry
L Candish, KD Collins, GC Cook, JJ Douglas… - Chemical …, 2021 - ACS Publications
In the pursuit of new pharmaceuticals and agrochemicals, chemists in the life science
industry require access to mild and robust synthetic methodologies to systematically modify …
industry require access to mild and robust synthetic methodologies to systematically modify …
The persistent radical effect in organic synthesis
Radical–radical couplings are mostly nearly diffusion‐controlled processes. Therefore, the
selective cross‐coupling of two different radicals is challenging and not a synthetically …
selective cross‐coupling of two different radicals is challenging and not a synthetically …
Alkyl carbon–carbon bond formation by Nickel/Photoredox cross‐coupling
JA Milligan, JP Phelan, SO Badir… - Angewandte Chemie …, 2019 - Wiley Online Library
The union of photoredox and nickel catalysis has resulted in a renaissance in radical
chemistry as well as in the use of nickel‐catalyzed transformations, specifically for carbon …
chemistry as well as in the use of nickel‐catalyzed transformations, specifically for carbon …
Photoinduced decarboxylative borylation of carboxylic acids
A Fawcett, J Pradeilles, Y Wang, T Mutsuga, EL Myers… - Science, 2017 - science.org
The conversion of widely available carboxylic acids into versatile boronic esters would be
highly enabling for synthesis. We found that this transformation can be effected by …
highly enabling for synthesis. We found that this transformation can be effected by …
Recent developments in organoboron chemistry: old dogs, new tricks
Organoboron reagents are one of the most widely studied and applied classes of reagent
throughout organic synthesis and catalysis. Not only are these reagents integral to many of …
throughout organic synthesis and catalysis. Not only are these reagents integral to many of …