Chiral metal–organic frameworks
In the past two decades, metal–organic frameworks (MOFs) or porous coordination polymers
(PCPs) assembled from metal ions or clusters and organic linkers via metal–ligand …
(PCPs) assembled from metal ions or clusters and organic linkers via metal–ligand …
Spontaneous deracemizations
Spontaneous deracemizations is a challenging, multidisciplinary subject in current chirality
research. In the absence of any chiral inductors, an achiral substance or a racemic …
research. In the absence of any chiral inductors, an achiral substance or a racemic …
Pillar-layered MOFs: functionality, interpenetration, flexibility and applications
Pillar-layered metal–organic frameworks (MOFs) are among the most interesting research
areas in crystalline materials. Due to the great number of reports related to pillar-layered …
areas in crystalline materials. Due to the great number of reports related to pillar-layered …
Synthesis, structure, and heterogeneous catalysis of a series of structurally diverse coordination polymers based on 5-nitroisophthalate
Four new coordination polymers have been synthesized based on a mixed-ligand strategy,
viz.,[Cu (4-ABPT)(HNIPA) 2H2O]· H2O, SSICG-1;[Cu2 (4-ABPT) 2 (HNIPA) 4]· H2O, SSICG …
viz.,[Cu (4-ABPT)(HNIPA) 2H2O]· H2O, SSICG-1;[Cu2 (4-ABPT) 2 (HNIPA) 4]· H2O, SSICG …
Amplification effect of circularly polarized luminescence induced from binaphthyl-based zinc (II) chiral coordination polymers
Y Wang, X Li, L Yang, WY Sun, C Zhu… - Materials Chemistry …, 2018 - pubs.rsc.org
Two novel binaphthyl-based dipyrrin zinc (II) chiral coordination polymers (R/S-P1) can be
synthesized by coordination reaction. R/S-P1 can exhibit stronger Cotton effects and …
synthesized by coordination reaction. R/S-P1 can exhibit stronger Cotton effects and …
Microporous Lead–Organic Framework for Selective CO2 Adsorption and Heterogeneous Catalysis
A novel microporous metal–organic framework,{[Pb4 (μ8-MTB) 2 (H2O) 4]· 5DMF· H2O} n (1;
MTB= methanetetrabenzoate and DMF= N, N′-dimethylformamide), was successfully …
MTB= methanetetrabenzoate and DMF= N, N′-dimethylformamide), was successfully …
Coordinatively Unsaturated Structurally Diverse Homophthalate-Based Cobalt (II) Coordination Polymers for Efficient Multicomponent Catalysis
Coordination polymers (CPs) have emerged as pioneering compounds due to their diverse
structural features and tunable properties. Numerous structural advantages, along with …
structural features and tunable properties. Numerous structural advantages, along with …
Chiral metal–organic frameworks constructed from four-fold helical chain SBUs for enantioselective recognition of α-hydroxy/amino acids
RX Yao, HH Fu, B Yu, XM Zhang - Inorganic Chemistry Frontiers, 2018 - pubs.rsc.org
The chiral recognition of racemic α-hydroxy/amino acids is an essential and challenging
mission because enantiomers may profoundly differ in biological function, pharmacology …
mission because enantiomers may profoundly differ in biological function, pharmacology …
Unprecedented homochiral 3D lanthanide coordination polymers with triple-stranded helical architecture constructed from a rigid achiral aryldicarboxylate ligand
LX You, SY **e, CC **a, SJ Wang, G **ong, YK He… - …, 2019 - pubs.rsc.org
Eight homochiral lanthanide coordination polymers, namely [Ln2L3 (H2O) 2] n· 4nH2O [Ln=
Sm (1); Eu (2); Gd (3); Tb (4); Dy (5); Ho (6); Er (7); Yb (8)], based on an achiral rigid ligand …
Sm (1); Eu (2); Gd (3); Tb (4); Dy (5); Ho (6); Er (7); Yb (8)], based on an achiral rigid ligand …
Synthesis and structural diversity of d 10 metal coordination polymers constructed from new semi-rigid bis (3-methyl-1 H-pyrazole-4-carboxylic acid) alkane ligands
M Cheng, Q Wang, J Bao, Y Wu, L Sun… - New Journal of …, 2017 - pubs.rsc.org
Three isomeric bis (3-methyl-1H-pyrazole-4-carboxylic acid) alkane ligands (H2L1, H2L2
and H2L3) were prepared via a two-step process from ethyl 3-methyl-1H-pyrazole-4 …
and H2L3) were prepared via a two-step process from ethyl 3-methyl-1H-pyrazole-4 …