[HTML][HTML] Modern X-ray spectroscopy: XAS and XES in the laboratory

P Zimmermann, S Peredkov, PM Abdala… - Coordination Chemistry …, 2020 - Elsevier
X-ray spectroscopy is an important tool for scientific analysis. While the earliest
demonstration experiments were realised in the laboratory, with the advent of synchrotron …

The comparison between single atom catalysis and surface organometallic catalysis

MK Samantaray, V D'Elia, E Pump, L Falivene… - Chemical …, 2019 - ACS Publications
Single atom catalysis (SAC) is a recent discipline of heterogeneous catalysis for which a
single atom on a surface is able to carry out various catalytic reactions. A kind of revolution …

Copper active sites in biology

EI Solomon, DE Heppner, EM Johnston… - Chemical …, 2014 - ACS Publications
On the basis of its generally accessible I/II redox couple and bioavailability, copper plays a
wide variety of roles in nature that mostly involve electron transfer (ET), O 2 binding …

Mn4Ca Cluster in Photosynthesis: Where and How Water is Oxidized to Dioxygen

J Yano, V Yachandra - Chemical reviews, 2014 - ACS Publications
Oxygen, which supports all aerobic life, is produced by photosynthetic water oxidation in
plants, algae, and cyanobacteria. The water-oxidation reaction probably first appeared in …

Reactivity of surface species in heterogeneous catalysts probed by in situ X-ray absorption techniques

S Bordiga, E Groppo, G Agostini… - Chemical …, 2013 - ACS Publications
Starting from the late seventies, the progressively increased availability of synchrotron light
sources allowed the execution of experiments requiring a high X-ray flux in a continuous …

X-ray emission spectroscopy evidences a central carbon in the nitrogenase iron-molybdenum cofactor

KM Lancaster, M Roemelt, P Ettenhuber, Y Hu… - Science, 2011 - science.org
Nitrogenase is a complex enzyme that catalyzes the reduction of dinitrogen to ammonia.
Despite insight from structural and biochemical studies, its structure and mechanism await …

High resolution 1s core hole X-ray spectroscopy in 3d transition metal complexes—electronic and structural information

P Glatzel, U Bergmann - Coordination chemistry reviews, 2005 - Elsevier
The creation of a 1s core hole in a 3d transition metal ion gives rise to an emission spectrum
that can be recorded using a crystal analyzer. K shell X-ray spectroscopy using an analyser …

High-resolution X-ray emission and X-ray absorption spectroscopy

F De Groot - Chemical Reviews, 2001 - ACS Publications
In this review, high-resolution X-ray emission and X-ray absorption spectroscopy will be
discussed. The focus is on the 3d transition-metal systems. To understand high-resolution X …

Probing valence orbital composition with iron Kβ X-ray emission spectroscopy

N Lee, T Petrenko, U Bergmann, F Neese… - Journal of the …, 2010 - ACS Publications
A systematic study of 12 ferric and ferrous Kβ X-ray emission spectra (XES) is presented.
The factors contributing to the Kβ main line and the valence to core region of the spectra are …

Advanced X-ray absorption and emission spectroscopy: in situ catalytic studies

J Singh, C Lamberti, JA van Bokhoven - Chemical Society Reviews, 2010 - pubs.rsc.org
Knowledge of the structure of catalysts is essential to understand their behavior, which
further facilitates development of an active, selective, and stable catalyst. Determining the …