[HTML][HTML] Modern X-ray spectroscopy: XAS and XES in the laboratory
X-ray spectroscopy is an important tool for scientific analysis. While the earliest
demonstration experiments were realised in the laboratory, with the advent of synchrotron …
demonstration experiments were realised in the laboratory, with the advent of synchrotron …
The comparison between single atom catalysis and surface organometallic catalysis
Single atom catalysis (SAC) is a recent discipline of heterogeneous catalysis for which a
single atom on a surface is able to carry out various catalytic reactions. A kind of revolution …
single atom on a surface is able to carry out various catalytic reactions. A kind of revolution …
Copper active sites in biology
On the basis of its generally accessible I/II redox couple and bioavailability, copper plays a
wide variety of roles in nature that mostly involve electron transfer (ET), O 2 binding …
wide variety of roles in nature that mostly involve electron transfer (ET), O 2 binding …
Mn4Ca Cluster in Photosynthesis: Where and How Water is Oxidized to Dioxygen
Oxygen, which supports all aerobic life, is produced by photosynthetic water oxidation in
plants, algae, and cyanobacteria. The water-oxidation reaction probably first appeared in …
plants, algae, and cyanobacteria. The water-oxidation reaction probably first appeared in …
Reactivity of surface species in heterogeneous catalysts probed by in situ X-ray absorption techniques
Starting from the late seventies, the progressively increased availability of synchrotron light
sources allowed the execution of experiments requiring a high X-ray flux in a continuous …
sources allowed the execution of experiments requiring a high X-ray flux in a continuous …
X-ray emission spectroscopy evidences a central carbon in the nitrogenase iron-molybdenum cofactor
Nitrogenase is a complex enzyme that catalyzes the reduction of dinitrogen to ammonia.
Despite insight from structural and biochemical studies, its structure and mechanism await …
Despite insight from structural and biochemical studies, its structure and mechanism await …
High resolution 1s core hole X-ray spectroscopy in 3d transition metal complexes—electronic and structural information
The creation of a 1s core hole in a 3d transition metal ion gives rise to an emission spectrum
that can be recorded using a crystal analyzer. K shell X-ray spectroscopy using an analyser …
that can be recorded using a crystal analyzer. K shell X-ray spectroscopy using an analyser …
High-resolution X-ray emission and X-ray absorption spectroscopy
F De Groot - Chemical Reviews, 2001 - ACS Publications
In this review, high-resolution X-ray emission and X-ray absorption spectroscopy will be
discussed. The focus is on the 3d transition-metal systems. To understand high-resolution X …
discussed. The focus is on the 3d transition-metal systems. To understand high-resolution X …
Probing valence orbital composition with iron Kβ X-ray emission spectroscopy
A systematic study of 12 ferric and ferrous Kβ X-ray emission spectra (XES) is presented.
The factors contributing to the Kβ main line and the valence to core region of the spectra are …
The factors contributing to the Kβ main line and the valence to core region of the spectra are …
Advanced X-ray absorption and emission spectroscopy: in situ catalytic studies
Knowledge of the structure of catalysts is essential to understand their behavior, which
further facilitates development of an active, selective, and stable catalyst. Determining the …
further facilitates development of an active, selective, and stable catalyst. Determining the …