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Generation and detection of reactive oxygen species in photocatalysis
Y Nosaka, AY Nosaka - Chemical reviews, 2017 - ACS Publications
The detection methods and generation mechanisms of the intrinsic reactive oxygen species
(ROS), ie, superoxide anion radical (• O2–), hydrogen peroxide (H2O2), singlet oxygen …
(ROS), ie, superoxide anion radical (• O2–), hydrogen peroxide (H2O2), singlet oxygen …
Environmental Implications of Hydroxyl Radicals (•OH)
The hydroxyl radical (• OH) is one of the most powerful oxidizing agents, able to react
unselectively and instantaneously with the surrounding chemicals, including organic …
unselectively and instantaneously with the surrounding chemicals, including organic …
Verifying the charge‐transfer mechanism in S‐Scheme heterojunctions using femtosecond transient absorption spectroscopy
C Cheng, J Zhang, B Zhu, G Liang… - Angewandte Chemie …, 2023 - Wiley Online Library
The S‐scheme heterojunction is flourishing in photocatalysis because it concurrently
realizes separated charge carriers and sufficient redox ability. Steady‐state charge transfer …
realizes separated charge carriers and sufficient redox ability. Steady‐state charge transfer …
Accurate identification of radicals by in-situ electron paramagnetic resonance in ultraviolet-based homogenous advanced oxidation processes
Accurate identification of radicals in advanced oxidation processes (AOPs) is important to
study the mechanisms on radical production and subsequent oxidation-reduction reaction …
study the mechanisms on radical production and subsequent oxidation-reduction reaction …
Chemical recycling of polystyrene to valuable chemicals via selective acid-catalyzed aerobic oxidation under visible light
Z Huang, M Shanmugam, Z Liu… - Journal of the …, 2022 - ACS Publications
Chemical recycling is one of the most promising technologies that could contribute to
circular economy targets by providing solutions to plastic waste; however, it is still at an early …
circular economy targets by providing solutions to plastic waste; however, it is still at an early …
Hydroxyl radicals dominate reoxidation of oxide-derived Cu in electrochemical CO2 reduction
Cuδ+ sites on the surface of oxide-derived copper (OD-Cu) are of vital importance in
electrochemical CO2 reduction reaction (CO2RR). However, the underlying reason for the …
electrochemical CO2 reduction reaction (CO2RR). However, the underlying reason for the …
Direct photo-oxidation of methane to methanol over a mono-iron hydroxyl site
Natural gas, consisting mainly of methane (CH4), has a relatively low energy density at
ambient conditions (~ 36 kJ l− 1). Partial oxidation of CH4 to methanol (CH3OH) lifts the …
ambient conditions (~ 36 kJ l− 1). Partial oxidation of CH4 to methanol (CH3OH) lifts the …
Long-term phototransformation of microplastics under simulated sunlight irradiation in aquatic environments: Roles of reactive oxygen species
K Zhu, H Jia, Y Sun, Y Dai, C Zhang, X Guo, T Wang… - Water Research, 2020 - Elsevier
Microplastics may experience photoaging and breakdown into nanoplastics in aquatic
environment as a result of long-term light irradiation. However, the underlying mechanisms …
environment as a result of long-term light irradiation. However, the underlying mechanisms …
EPR evidence for mechanistic diversity of Cu (II)/peroxygen oxidation systems by tracing the origin of DMPO spin adducts
Electron paramagnetic resonance (EPR) has been extensively used for the identification of
free radicals that are generated from advanced oxidation processes (AOPs) so as to …
free radicals that are generated from advanced oxidation processes (AOPs) so as to …
Role of superoxide radical and singlet oxygen in peroxymonosulfate activation by iron-doped bone char for efficient acetaminophen degradation
Y Zeng, F Wang, D He, J Sun, J Li, H Luo… - Chemical Engineering …, 2023 - Elsevier
Bone char is a hydroxyapatite-rich product obtained by calcining animal bones. However,
the role of inorganic hydroxyapatite is often overlooked in bone char-catalyzed persulfate …
the role of inorganic hydroxyapatite is often overlooked in bone char-catalyzed persulfate …