Challenges and strategies towards single‐crystalline Ni‐rich layered cathodes

L Ni, S Zhang, A Di, W Deng, G Zou… - Advanced energy …, 2022 - Wiley Online Library
The ever‐increasing energy density requirements in electric vehicles (EVs) have boosted
the development of Ni‐rich layered oxide cathodes for state‐of‐the‐art lithium‐ion batteries …

Nickel-rich and cobalt-free layered oxide cathode materials for lithium ion batteries

Y Luo, H Wei, L Tang, Z Wang, Z He, C Yan… - Energy storage …, 2022 - Elsevier
For conventional cathode materials, cobalt plays an important role, but the cobalt content of
lithium battery cathode materials must be reduced because of the scarcity of cobalt …

Compositionally complex do** for zero-strain zero-cobalt layered cathodes

R Zhang, C Wang, P Zou, R Lin, L Ma, L Yin, T Li, W Xu… - Nature, 2022 - nature.com
The high volatility of the price of cobalt and the geopolitical limitations of cobalt mining have
made the elimination of Co a pressing need for the automotive industry. Owing to their high …

Sustainable electric vehicle batteries for a sustainable world: perspectives on battery cathodes, environment, supply chain, manufacturing, life cycle, and policy

Z Yang, H Huang, F Lin - Advanced Energy Materials, 2022 - Wiley Online Library
Li‐ion batteries (LIBs) can reduce carbon emissions by powering electric vehicles (EVs) and
promoting renewable energy development with grid‐scale energy storage. However, LIB …

Cracking vs. surface reactivity in high-nickel cathodes for lithium-ion batteries

S Lee, L Su, A Mesnier, Z Cui, A Manthiram - Joule, 2023 - cell.com
High-nickel layered oxide cathodes LiNi x Mn y Co z O 2 (NMC) experience microcracks
during cycling. This can expose fresh cathode surfaces for parasitic reactions and isolate …

Oxygen hole formation controls stability in LiNiO2 cathodes

AR Genreith-Schriever, H Banerjee, AS Menon… - Joule, 2023 - cell.com
Ni-rich lithium-ion cathode materials achieve both high voltages and capacities but are
prone to structural instabilities and oxygen loss. The origin of the instability lies in the …

High-energy all-solid-state lithium batteries enabled by Co-free LiNiO2 cathodes with robust outside-in structures

L Wang, A Mukherjee, CY Kuo, S Chakrabarty… - Nature …, 2024 - nature.com
A critical current challenge in the development of all-solid-state lithium batteries (ASSLBs) is
reducing the cost of fabrication without compromising the performance. Here we report a …

Assessing the Intrinsic Roles of Key Dopant Elements in High‐Nickel Layered Oxide Cathodes in Lithium‐Based Batteries

Z Cui, Z Guo, A Manthiram - Advanced Energy Materials, 2023 - Wiley Online Library
A rational compositional design is critical for utilizing LiNiO2‐based cathodes with Ni
contents> 90% as promising next‐generation cathode materials. Unfortunately, the lack of a …

[HTML][HTML] Crack-free single-crystalline Co-free Ni-rich LiNi0. 95Mn0. 05O2 layered cathode

L Ni, R Guo, S Fang, J Chen, J Gao, Y Mei, S Zhang… - EScience, 2022 - Elsevier
The rapid growth in global electric vehicles (EVs) sales has promoted the development of
Co-free, Ni-rich layered cathodes for state-of-the-art high energy-density, inexpensive …

High‐nickel NMA: a cobalt‐free alternative to NMC and NCA cathodes for lithium‐ion batteries

W Li, S Lee, A Manthiram - Advanced materials, 2020 - Wiley Online Library
Abstract High‐nickel LiNi1− x− yMnxCoyO2 (NMC) and LiNi1− x− yCoxAlyO2 (NCA) are the
cathode materials of choice for next‐generation high‐energy lithium‐ion batteries. Both …