Two-dimensional polymers and polymerizations
Synthetic chemists have developed robust methods to synthesize discrete molecules, linear
and branched polymers, and disordered cross-linked networks. However, two-dimensional …
and branched polymers, and disordered cross-linked networks. However, two-dimensional …
The chemistry and applications of flexible porous coordination polymers
Since the late 1990s, much progress has been made in the field of the chemistry of flexible
porous coordination polymers (PCPs). Various PCP architectures have been recognized …
porous coordination polymers (PCPs). Various PCP architectures have been recognized …
Frustrated flexibility in metal-organic frameworks
R Pallach, J Keupp, K Terlinden… - Nature …, 2021 - nature.com
Stimuli-responsive flexible metal-organic frameworks (MOFs) remain at the forefront of
porous materials research due to their enormous potential for various technological …
porous materials research due to their enormous potential for various technological …
Porous flexible frameworks: origins of flexibility and applications
Porous crystalline frameworks including zeolites, metal–organic frameworks (MOFs),
covalent organic frameworks (COFs) and hydrogen-bonded organic frameworks (HOFs) …
covalent organic frameworks (COFs) and hydrogen-bonded organic frameworks (HOFs) …
Negative gas adsorption transitions and pressure amplification phenomena in porous frameworks
Nanoporous solids offer a wide range of functionalities for industrial, environmental, and
energy applications. However, only a limited number of porous materials are responsive, ie …
energy applications. However, only a limited number of porous materials are responsive, ie …
Cooperative light-induced breathing of soft porous crystals via azobenzene buckling
Although light is a prominent stimulus for smart materials, the application of photoswitches
as light-responsive triggers for phase transitions of porous materials remains poorly …
as light-responsive triggers for phase transitions of porous materials remains poorly …
Computational modeling of reticular materials: The past, the present, and the future
Reticular materials rely on a unique building concept where inorganic and organic building
units are stitched together giving access to an almost limitless number of structured ordered …
units are stitched together giving access to an almost limitless number of structured ordered …
Towards modeling spatiotemporal processes in metal–organic frameworks
Metal–organic frameworks (MOFs) are hybrid materials constructed from metal clusters
linked by organic linkers, which can be engineered for target functional applications in, for …
linked by organic linkers, which can be engineered for target functional applications in, for …
Challenges in modelling dynamic processes in realistic nanostructured materials at operating conditions
V Van Speybroeck - … Transactions of the Royal Society A, 2023 - royalsocietypublishing.org
The question is addressed in how far current modelling strategies are capable of modelling
dynamic phenomena in realistic nanostructured materials at operating conditions …
dynamic phenomena in realistic nanostructured materials at operating conditions …
On the role of history-dependent adsorbate distribution and metastable states in switchable mesoporous metal-organic frameworks
A unique feature of metal-organic frameworks (MOFs) in contrast to rigid nanoporous
materials is their structural switchabilty offering a wide range of functionality for sustainable …
materials is their structural switchabilty offering a wide range of functionality for sustainable …