Reactive p-block cations stabilized by weakly coordinating anions
TA Engesser, MR Lichtenthaler, M Schleep… - Chemical Society …, 2016 - pubs.rsc.org
The chemistry of the p-block elements is a huge playground for fundamental and applied
work. With their bonding from electron deficient to hypercoordinate and formally hypervalent …
work. With their bonding from electron deficient to hypercoordinate and formally hypervalent …
Amphoteric reactivity of metal–oxygen complexes in oxidation reactions
Mononuclear metal–oxygen species, such as metal-superoxo,-peroxo,-hydroperoxo and-
oxo complexes, are key intermediates involved in dioxygen activation and oxidation …
oxo complexes, are key intermediates involved in dioxygen activation and oxidation …
Lewis Base Mediated Autoionization of GeCl2 and SnCl2
Cationic and anionic species of heavier low-valent group 14 elements are intriguing targets
in main group chemistry due to their synthetic potential and industrial applications. In the …
in main group chemistry due to their synthetic potential and industrial applications. In the …
Stabilization of a two-coordinate [GeCl]+ cation by simultaneous σ and π donation from a monodentate carbodiphosphorane
Give me four: The synthesis, structure, and reactivity of [GeCl]+ and [SnCl]+ cations bearing
a carbodiphosphorane as ancillary ligand are presented. In the Ge compound, simultaneous …
a carbodiphosphorane as ancillary ligand are presented. In the Ge compound, simultaneous …
Cations and dications of heavier group 14 elements in low oxidation states
Cations and dications of heavier group 14 elements in their low oxidation state have
received widespread attention in recent years. The journey started with the isolation of a …
received widespread attention in recent years. The journey started with the isolation of a …
Isolation and Structure of Germylene‐Germyliumylidenes Stabilized by N‐Heterocyclic Imines
The ditopic germanium complex FGe (NIPr) 2Ge [BF4](3 [BF4]; IPr= 1, 3‐bis (2, 6‐
diisopropylphenyl) imidazolin‐2‐ylidene) is prepared by the reaction of the amino (imino) …
diisopropylphenyl) imidazolin‐2‐ylidene) is prepared by the reaction of the amino (imino) …
Hafnocene-based bicyclo [2.1. 1] hexene germylenes–formation, reactivity, and structural flexibility
Z Dong, K Bedbur, M Schmidtmann… - Journal of the American …, 2018 - ACS Publications
2, 5-Disilylsubstituted germole dianions 1 react with hafnocene dichloride to give hafnocene-
based bicyclo [2.1. 1] hexene germylenes 3. Their formation proceeds via hafnocene …
based bicyclo [2.1. 1] hexene germylenes 3. Their formation proceeds via hafnocene …
Synthesis and Unexpected Reactivity of Germyliumylidene Hydride [:GeH]+ Stabilized by a Bis(N-heterocyclic carbene)borate Ligand
Employing the potassium salt of the monoanionic bis (NHC) borate 1 (NHC= NH eterocyclic
C arbene) enables the synthesis and isolation of the bis (NHC) borate-stabilized …
C arbene) enables the synthesis and isolation of the bis (NHC) borate-stabilized …
Coordination complexes of silicon and germanium halides with neutral ligands
W Levason, G Reid, W Zhang - Coordination Chemistry Reviews, 2011 - Elsevier
The coordination chemistry of silicon (IV) and (II) and germanium (IV) and (II) halides with
neutral donor ligands from groups 15 (N, P or As) and 16 (O, S or Se) is reviewed; N …
neutral donor ligands from groups 15 (N, P or As) and 16 (O, S or Se) is reviewed; N …
Intramolecular donor-stabilized tetra-coordinated germanium (iv) di-cations and their Lewis acidic properties
We report the first examples of intramolecular phosphine-stabilized tetra-coordinated
germanium (IV) di-cationic compounds:[LiPr2Ge][CF3SO3] 23iPr and [LPh2Ge][CF3SO3] …
germanium (IV) di-cationic compounds:[LiPr2Ge][CF3SO3] 23iPr and [LPh2Ge][CF3SO3] …